Dimethyl Phthalate, a Neutral Bidentate Oxygen-Donor Ligand to Divalent Metal Ions
1977 ◽
Vol 32
(11)
◽
pp. 1284-1286
◽
Keyword(s):
A series of new coordination compounds is reported with dimethyl phthalate (MPH) as the ligand, viz. [M(MPH)3](InCl4)2 with M=Mg(II), Ca(II), Mn(II), Fe(II), Co(II), Ni(II), and Zn(II). Each of the metal ions is bonded to three dimethyl phthalate molecules, the six carbonyl oxygens forming a regular octahedron. The carbonyl stretching vibration shifts to lower frequencies, the carbonyl bending vibration shifts to higher frequencies. The magnitudes of the shifts of these vibrations, the frequencies of the metal-ligand vibrations, and the melting points follow the Irving-Williams sequence.
Keyword(s):
Keyword(s):
Keyword(s):
1977 ◽
Vol 39
(10)
◽
pp. 1847-1848
◽
Keyword(s):
The thermodynamic metal–ligand stability constants of hydroxamic acids with some divalent metal ions
1989 ◽
pp. 1117-1123
◽
Keyword(s):
1999 ◽
Vol 64
(10)
◽
pp. 621-635
◽
Keyword(s):
1976 ◽
Vol 12
(3)
◽
pp. 277-284
◽
Keyword(s):
1991 ◽
Vol 81
(4)
◽
pp. 462-466
◽
2019 ◽
Vol 11
(1)
◽
pp. 01021-1-01021-5