The Stereochemistry of P-N Bond Cleavage in the Staudinger -Wittig-type Reaction of 2-Anilido-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidine-2-thiones
1978 ◽
Vol 33
(7)
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pp. 782-785
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AbstractBoth isomers of 2-anilido-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidine-2-thiones (2 a and 2 b) derived from (-)ephedrine were obtained and converted to corresponding 2-thiomethyl derivatives (3 a and 3 b). The Staudinger-Wittig-type reaction of P-N bond cleavage was found to proceed with full retention of configuration at P-atom involved into five-membered ring system.
1983 ◽
Vol 241
(3)
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pp. 281-287
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Keyword(s):
1988 ◽
Vol 43
(8)
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pp. 959-962
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1992 ◽
Vol 47
(2)
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pp. 171-174
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2002 ◽
Vol 43
(27)
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pp. 4861-4864
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