Hochdrucksynthese quaternärer Chalkogenidhalogenide AB2X3Y (A = Cu, Ag; B = In; X = S, Se, Te; Y = Cl, Br, I)/High Pressure Synthesis of Quaternary Chalcogenide Halogenides AB2X3Y (A = Cu, Ag; B = In; X = S, Se, Te; Y = Cl, Br, I)
1983 ◽
Vol 38
(2)
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pp. 155-160
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Abstract Quaternary compounds AB2X3Y (A = Cu, Ag; B = In; X = S, Se, Te; Y = Cl, Br, I) could be synthesized at high pressures and temperatures. The crystal structures found are defect-zincblende (AgIn2Se3I, AgIn2Te3l, CuIn2Se3Br, CuIn2Se3I, CuIn2Te3Cl, CuIn2Te3Br, CuInTe3I), spinel (AgIn2S3Cl, AgIn2S3Br, AgIn2Se3Cl, AgIn2Se3Br, AgIn2Se3l) and defect-rocksalt (AgIn2Te3Cl, AgIn2Te3Br). A second form of CuIn2Se3l is intermediate between the zincblende and spinel structure. A survey of the different reaction pathways of AB-B2X3 mixtures at high pressures and temperatures is given.
2002 ◽
Vol 330-332
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pp. 152-156
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1988 ◽
Vol 43
(2)
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pp. 240-242
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2004 ◽
Vol 370
(1-2)
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pp. 110-113
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2002 ◽
Vol 163
(1)
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pp. 77-83
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