Synthese und Struktur von C5Me5Pd(PR3)X: Palladiumkomplexe mit einem unsymmetrisch gebundenen Pentamethylcyclopentadienylring [1] / Synthesis and Structure of C5Me5Pd(PR3)X: Palladium Complexes with an Unsymmetrically Bonded Pentamethylcyclopentadienyl Ring [1]
1983 ◽
Vol 38
(6)
◽
pp. 733-737
◽
Abstract The complexes C5Me5Pd(PR3)X (1-4) are prepared from [Cl(PR3)Pd]2(μ-OCOCH3)2 and TIC5Me5. Attempts to replace the halide ligand by a second C5Me5 or a C5H5 unit remained unsuccessful. The X-ray structure analysis of C5Me5Pd[P(i-Pr)3]Cl (3) indicates that the five-membered ring shows a tendency of η1-bonding towards the metal.
1992 ◽
Vol 47
(2)
◽
pp. 171-174
◽
1994 ◽
Vol 49
(3)
◽
pp. 309-314
◽
1989 ◽
Vol 44
(7)
◽
pp. 796-799
◽
Keyword(s):
1990 ◽
Vol 45
(11)
◽
pp. 1597-1599
◽
Keyword(s):