Kristallstruktur von Cs2[B6H5(SCN)]/ Crystal Structure of Cs2[B6H5(SCN)]
1998 ◽
Vol 53
(8)
◽
pp. 816-818
◽
Keyword(s):
Abstract By reaction of [B6H6]2-with (SCN)2 in dichloromethane at -80 C° the thiocyanatohexaborate anion is formed and can be isolated by ion exchange chromatography on diethylaminoethyl (DEAE) cellulose. The X-ray structure determination of Cs2[B6H5(SCN)] (orthorhombic, space group Pbca with a = 9.506(5), b = 10.644(5), c = 21.857(5) Å, Z = 8) reveals that the SCN substituent is bonded via the S atom with the B-S distance of 1.885(9) Å and the B-S-C angle of 99.8(5)°. The SCN group is nearly linear (179.9(9)°).
1996 ◽
Vol 51
(8)
◽
pp. 1061-1063
◽
1997 ◽
Vol 52
(8)
◽
pp. 975-977
◽
1993 ◽
Vol 48
(12)
◽
pp. 1727-1731
◽
1994 ◽
Vol 49
(9)
◽
pp. 1263-1266
◽
2000 ◽
Vol 215
(5)
◽
2015 ◽
Vol 70
(3)
◽
pp. 191-196
◽
Keyword(s):
1995 ◽
Vol 50
(1)
◽
pp. 66-70
◽
Keyword(s):