Synthesis of methyl 4-dihydrotrisporate B and methyl trisporate B, morphogenetic factors of Zygomycetes fungi

2018 ◽  
Vol 73 (1-2) ◽  
pp. 59-66 ◽  
Author(s):  
Yoko Nakamura ◽  
Christian Paetz ◽  
Wilhelm Boland
Keyword(s):  
Uv Irradiation ◽  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Stability Studies ◽  
Synthesis Route ◽  
Morphogenetic Factors

Abstract(9Z)-Methyl 4-dihydrotrisporate B and (9Z)-methyl trisporate B, pheromones of Zygomycetes fungi, have been synthesized using Stille cross-coupling from previously described cyclohexenone precursors. Conducting the coupling without protection groups allowed for a short and stereospecific synthesis route of the late trisporoids. Stability studies for both the compounds revealed (9Z)-methyl trisporate B to be very unstable against UV irradiation.

Utilization of Sequential Palladium-Catalyzed Cross-Coupling Reactions in the Stereospecific Synthesis of Trisubstituted Olefins

2009 ◽  
Vol 13 (3) ◽  
pp. 598-606 ◽  
Author(s):  
Ioannis N. Houpis ◽  
Didier Shilds ◽  
Ulrike Nettekoven ◽  
Anita Schnyder ◽  
Erhart Bappert ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Trisubstituted Olefins ◽  
Palladium Catalyzed

Stereospecific Synthesis of Chalcogenoenynes by Palladium-Catalyzed Cross-Coupling Reaction

Synlett ◽  
2003 ◽  
pp. 0579-0581 ◽  
Author(s):  
Gilson Zeni ◽  
Cristina W. Nogueira ◽  
Jesus M. Pena ◽  
Cristiane Pilissão ◽  
Paulo H. Menezes ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed

Stereospecific Synthesis of Alkenes by Eliminative Cross-Coupling of Enantioenriched sp3 -Hybridized Carbenoids

2016 ◽  
Vol 128 (40) ◽  
pp. 12473-12477 ◽  
Author(s):  
Zhenhua Wu ◽  
Xun Sun ◽  
Kristin Potter ◽  
Yang Cao ◽  
Lev N. Zakharov ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Stereospecific Synthesis

Hiyama Cross-Coupling Reaction in the Stereospecific Synthesis of Retinoids

2010 ◽  
Vol 12 (16) ◽  
pp. 3728-3728
Author(s):  
Javier Montenegro ◽  
Julián Bergueiro ◽  
Carlos Saá ◽  
Susana López
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Cross Coupling Reaction

Stereospecific Synthesis of Chalcogenoenynes by Palladium-Catalyzed Cross-Coupling Reaction.

ChemInform ◽  
2003 ◽  
Vol 34 (30) ◽  
Author(s):  
Gilson Zeni ◽  
Cristina W. Nogueira ◽  
Jesus M. Pena ◽  
Cristiane Pilissao ◽  
Paulo H. Menezes ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed
Sign in / Sign up

Export Citation Format

Share Document