Leaching Chemistry of Defense Borosilicate Glass

1982 ◽  
Vol 15 ◽  
Author(s):  
Richard M. Wallace ◽  
George G. Wicks
Keyword(s):  
Predictive Model ◽  
Borosilicate Glass ◽  
Waste Glass ◽  
Savannah River ◽  
Short Term ◽  
Glass Corrosion ◽  
Savannah River Plant ◽  
Plant Waste ◽  
Long Term Behavior

Studies of the leachability of waste glass have been in progress at Savannah River Laboratory (SRL) for several years. The principal objective of these studies has been to predict the long-term behavior of Savannah River Plant waste glass when stored in a repository. Such predictions can be made from the results of short-term tests only if the mechanisms of waste glass corrosion are understood. Determining the mechanisms of corrosion and developing a predictive model have therefore been a major thrust of our work.

Simulation of the Waste Glass Behavior in a Loamy Soil of the Wet Repository Site

2000 ◽  
Vol 663 ◽  
Author(s):  
M.I. Ojovan ◽  
N.V. Ojovan ◽  
I.V. Startceva ◽  
G.N. Chuikova ◽  
A.S. Barinov
Keyword(s):  
Borosilicate Glass ◽  
Field Data ◽  
Waste Glass ◽  
Loamy Soil ◽  
Model Calculations ◽  
Near Surface ◽  
Glass Corrosion ◽  
Radionuclide Release ◽  
Glass Behavior

ABSTRACTA model developed for description of waste glass corrosion has been applied to assess the radionuclide release from real radioactive (intermediate level) vitrified material over extended storage periods. Field data generated during the long-term testing of the prototype waste glass packages were mathematically processed and the derived parameters used in model calculations. Regardless of the corrosive saturated conditions of the wet near-surface repository, the fairly high safety of trench disposal has been demonstrated for borosilicate glass containing real NPP- operational waste.

scholarly journals (M,β)-Stability of Positive Linear Systems

2016 ◽  
Vol 2016 ◽  
pp. 1-11 ◽  
Author(s):  
Octavian Pastravanu ◽  
Mihaela-Hanako Matcovschi
Keyword(s):  
Linear System ◽  
Linear Systems ◽  
Transient Behavior ◽  
Short Term ◽  
Time Dynamics ◽  
The Right ◽  
Long Term Behavior ◽  
Stability Concept

The main purpose of this work is to show that the Perron-Frobenius eigenstructure of a positive linear system is involved not only in the characterization of long-term behavior (for which well-known results are available) but also in the characterization of short-term or transient behavior. We address the analysis of the short-term behavior by the help of the “(M,β)-stability” concept introduced in literature for general classes of dynamics. Our paper exploits this concept relative to Hölder vectorp-norms,1≤p≤∞, adequately weighted by scaling operators, focusing on positive linear systems. Given an asymptotically stable positive linear system, for each1≤p≤∞, we prove the existence of a scaling operator (built from the right and left Perron-Frobenius eigenvectors, with concrete expressions depending onp) that ensures the best possible values for the parametersMandβ, corresponding to an “ideal” short-term (transient) behavior. We provide results that cover both discrete- and continuous-time dynamics. Our analysis also captures the differences between the cases where the system dynamics is defined by matrices irreducible and reducible, respectively. The theoretical developments are applied to the practical study of the short-term behavior for two positive linear systems already discussed in literature by other authors.

Effects of Alpha, Gamma, and Alpha-Recoil Radiation on Borosilicate Glass Containing Savannah River Plant Defense High-Level Nuclear Waste

1981 ◽  
Vol 6 ◽  
Author(s):  
Ned E. Bibler
Keyword(s):  
Borosilicate Glass ◽  
Deionized Water ◽  
Savannah River ◽  
Γ Radiation ◽  
Leach Rate ◽  
Geologic Storage ◽  
Savannah River Plant ◽  
Pb Ions ◽  
High Level ◽  
Doped Glass

ABSTRACTAt the Savannah River Plant, the reference process for the immobilization of defense high-level waste (DHLW) for geologic storage is vitrification into borosilicate glass. During geologic storage for 106y, the glass would be exposed to ∼3 × 1010 rad of β radiation, ∼1010 rad of γ radiation, and 1018 particles/g glass for both α and α-recoil radiation. This paper discusses tests of the effect of these radiations on the leachability and density of the glass. No effect of the radiations was detected that reduced the effectiveness of the glass for long-term storage of DHLW even at doses corresponding to 106 years storage for the actual glass. For the tests, glass containing simulated DHLW was prepared from frit of the reference composition. Three methods were used to irradiate the glass: external irradiations with beams of ∼200 keV or Pb ions, internal irradiations with Cm–244 doped glass, and external irradiations with Co–60 γ rays. Results with both Xe and Pb ions indicate that a dose of 3 × 1013 ions/cm2 (simulating >106 years storage) does not significantly increase the leachability of the glass in deionized water. Tests with Cm–244 doped glass show no increase in leach rate in deionized water up to a dose of 1.3 × 1018 α and α-recoils/g glass. The density of the Cm–244 doped glass has decreased by 1% at a dose of 1018 particles/g glass. With γ-radiation, the density has changed by <0.05% at a dose of 8.5 × 1010 rad. Results of leach tests in deionized water and brine indicated that this very large dose of γ-radiation increased the leach rate by only 20%. Also, the leach rates are 3 to 4 times lower in brine.

Multibarrier Storage of Savannah River Plant Waste

1980 ◽  
pp. 231-238
Author(s):  
M. D. Dukes ◽  
W. C. Mosley ◽  
W. N. Rankin ◽  
M. H. Tennant ◽  
J. R. Wiley
Keyword(s):  
Savannah River ◽  
Savannah River Plant ◽  
Plant Waste
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