Utilization of Waste Glass in Autoclaved Silica–Lime Materials

This paper aims to investigate the possibility of using waste glass of different colours as a complete substitute for quartz sand in autoclaved silica–lime samples. On the one hand, this increases the possibility of recycling waste glass; on the other hand, it allows obtaining autoclaved materials with better properties. In this research, reference samples with quartz sand (R) and white (WG), brown (BG), and green (GG) waste container glass were made. Parameters such as compressive strength, bulk density, and water absorption were examined on all samples. The samples were examined using a scanning electron microscope with an energy dispersive spectroscopy detector (SEM/EDS) and subjected to X-ray diffraction (XRD) analysis. The WG samples showed 187% higher compressive strength, BG by 159%, and GG by 134% compared to sample R. In comparison to the reference sample, volumetric density was 16.8% lower for sample WG, 13.2% lower for BG, and 7.1% lower for GG. Water absorption increased as bulk density decreased. The WG sample achieved the highest water absorption value, 15.84%. An X-ray diffraction analysis confirmed the presence of calcite, portlandite, and tobermorite phases. Depending on the silica aggregate used, there were differences in phase composition linked to compressive strength. Hydrated calcium silicates with varying crystallisation degrees were visible in the microstructure image.

Concrete with Partial Substitution of Waste Glass and Recycled Concrete Aggregate

The current practice of concrete is thought to be unsuitable because it consumes large amounts of cement, sand, and aggregate, which causes depletion of natural resources. In this study, a step towards sustainable concrete was made by utilizing recycled concrete aggregate (RCA) as a coarse aggregate. However, researchers show that RCA causes a decrease in the performance of concrete due to porous nature. In this study, waste glass (WG) was used as a filler material that filled the voids between RCA to offset its negative impact on concrete performance. The substitution ratio of WG was 10, 20, or 30% by weight of cement, and RCA was 20, 40, and 60% by weight of coarse aggregate. The slump cone test was used to assess the fresh property, while compressive, split tensile, and punching strength were used to assess the mechanical performance. Test results indicated that the workability of concrete decreased with substitution of WG and RCA while mechanical performance improved up to a certain limit and then decreased due to lack of workability. Furthermore, a statical tool response surface methodology was used to predict various strength properties and optimization of RCA and WG.

Influence of Waste Glass Powder Addition on the Microstructure and Mechanical Properties of Autoclaved Building Materials

Lime quartz samples in which ground quartz sand was gradually substituted with waste glass powder (GP) were obtained under hydrothermal conditions to determine the influence of GP addition on the microstructure (observed by SEM), phase composition (analyzed by XRD), and compressive strength of autoclaved building materials. An additional series containing analytical grade NaOH and no GP was formed to evaluate the effect of sodium ions on tobermorite formation and its impact on the mechanical properties of the samples. GP addition hindered the formation of tobermorite during autoclaving. Instead, a higher amount of an amorphous and semi-crystalline C–S–H phase formed, leading to the densification of the composite matrix. Nevertheless, tobermorite-like structures were found during both XRD and SEM analyses, proving that the presence of small amounts of Al3+ ions allowed, to an extent, for the stabilization of the phase despite the high sodium content. The compressive strength values indicate that the presence of alkali in the system and the resulting formation of additional portions of C–S–H have a beneficial influence on the mechanical properties of autoclaved composites. However, the effect fades with increasing glass powder content which, together with a slight expansion of the samples, suggests that at high sand substitution levels, an alkali–silica reaction takes place.