Motional Correlation Time of Dilute 111Cd Impurities in Se-Rich Liquid Se-Te Alloys
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ABSTRACTThe motional correlation time, τc, in liquid Se and Se-rich Se-Te alloys has been investigated between 500 and 900°C using time differential perturbed angular correlations of y-rays from dilute 111Cd impurities. In all alloys we find τc ∝ exp (E0/kT) at low T where E0 = 0.36 eV. τC deviates from this relation at high T. At low T, τCis tentatively identified as the lifetime of a Cd to host molecule bond, and at high T as the average lifetime of bonds in the host molecule.
1996 ◽
Vol 51
(5-6)
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pp. 396-410
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1985 ◽
Vol 82
(3)
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pp. 1271-1274
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1983 ◽
Vol 102
(2-3)
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pp. 277-280
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1973 ◽
Vol 260
(2)
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pp. 131-146
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