Novel and Highly Selective Conversion of Alcohols , Thiols and Trimethylsilyl Ethers to Alkyl Nitrites with 2,4,6-Trichloro[1,3,5]triazine/n-Bu4NNO2 System

2006 ◽  
Vol 3 (3) ◽  
pp. 220-224 ◽  
Author(s):  
Elham Roohi ◽  
Batool Akhlaghinia
Keyword(s):  
Alkyl Nitrites ◽  
Selective Conversion ◽  
Trimethylsilyl Ethers ◽  
Conversion Of Alcohols

Copper-Catalyzed Carbene Insertion into O−H Bonds:  High Selective Conversion of Alcohols into Ethers

2003 ◽  
Vol 22 (14) ◽  
pp. 2914-2918 ◽  
Author(s):  
M. Esther Morilla ◽  
M. Jesus Molina ◽  
M. Mar Díaz-Requejo ◽  
Tomás R. Belderraín ◽  
M. Carmen Nicasio ◽  
...  
Keyword(s):  
Selective Conversion ◽  
Carbene Insertion ◽  
Conversion Of Alcohols

scholarly journals Selective conversion of alcohols in water to carboxylic acids by in situ generated ruthenium trans dihydrido carbonyl PNP complexes

2014 ◽  
Vol 43 (46) ◽  
pp. 17248-17254 ◽  
Author(s):  
Jong-Hoo Choi ◽  
Leo E. Heim ◽  
Mike Ahrens ◽  
Martin H. G. Prechtl
Keyword(s):  
Carboxylic Acids ◽  
Direct Conversion ◽  
Primary Alcohols ◽  
Selective Conversion ◽  
Conversion Of Alcohols

In this work, we present a mild method for direct conversion of primary alcohols into carboxylic acids with the use of water as an oxygen source.

Conversion of Alcohols, Thiols, and Trimethylsilyl Ethers to Alkyl Cyanides Using Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/n-Bu4NCN.

ChemInform ◽  
2004 ◽  
Vol 35 (32) ◽  
Author(s):  
Nasser Iranpoor ◽  
Habib Firouzabadi ◽  
Batool Akhlaghinia ◽  
Najmeh Nowrouzi
Keyword(s):  
Trimethylsilyl Ethers ◽  
Conversion Of Alcohols

4-Aminophenyldiphenylphosphinite (APDPP), a new heterogeneous and acid scavenger phosphinite — Conversion of alcohols, trimethylsilyl, and tetrahydropyranyl ethers to alkyl halides with halogens or N-halosuccinimides

2006 ◽  
Vol 84 (7) ◽  
pp. 1006-1012 ◽  
Author(s):  
Nasser Iranpoor ◽  
Habib Firouzabadi ◽  
Mohammad Gholinejad
Keyword(s):  
Trimethylsilyl Ether ◽  
Alkyl Halide ◽  
Alkyl Halides ◽  
Amino Group ◽  
Efficient Conversion ◽  
Trimethylsilyl Ethers ◽  
Simple Filtration ◽  
Tetrahydropyranyl Ether ◽  
Conversion Of Alcohols

A new heterogeneous phosphinite, 4-aminophenyldiphenylphosphinite (APDPP), is prepared and used for the efficient conversion of alcohols, trimethylsilyl ethers, and tetrahydropyranyl ethers to their corresponding bromides, iodides, and chlorides in the presence of molecular halogens or N-halosuccinimides. The amino group in this phosphinite acts as an acid scavenger and removes the produced acid. A simple filtration easily removes the phosphinate by-product.Key words: 4-aminophenyldiphenylphosphinite, alcohol, trimethylsilyl ether, tetrahydropyranyl ether, alkyl halide.

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