Complete Deconstruction of SF6 by an Aluminium(I) Compound

10.26434/chemrxiv.14687331.v1 ◽

2021 ◽

Author(s):

Daniel Sheldon ◽

Mark Crimmin

Keyword(s):

Greenhouse Gas ◽

Room Temperature ◽

Reaction Sequence ◽

Organic Products ◽

Temperature Activation ◽

Net Transfer

The room-temperature activation of SF6, a potent greenhouse gas, is reported using a monovalent aluminium(I) reagent to form well-defined aluminium(III) fluoride and aluminium(III) sulfide products. New reactions have been developed to utilise the aluminium(III) fluoride and aluminium(III) sulfide as a nucleophilic source of F– and S2– for a range of electrophiles. The overall reaction sequence results in the net transfer of fluorine or sulfur atoms from an environmentally detrimental gas to useful organic products.

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Complete Deconstruction of SF6 by an Aluminium(I) Compound

Chemical Communications ◽

10.1039/d1cc02838c ◽

2021 ◽

Author(s):

Daniel James Sheldon ◽

Mark Richard Crimmin

Keyword(s):

Greenhouse Gas ◽

Room Temperature ◽

Temperature Activation

The room-temperature activation of SF6, a potent greenhouse gas, is reported using a monovalent aluminium(I) reagent to form well-defined aluminium(III) fluoride and aluminium(III) sulfide products. New reactions have been developed...

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Role of the Metal Surface on the Room Temperature Activation of the Alcohol and Amino Groups of p-Aminophenol

The Journal of Physical Chemistry C ◽

10.1021/acs.jpcc.0c06101 ◽

2020 ◽

Vol 124 (36) ◽

pp. 19655-19665

Author(s):

Nerea Ruiz del Árbol ◽

Irene Palacio ◽

Carlos Sánchez-Sánchez ◽

Gonzalo Otero-Irurueta ◽

José I. Martínez ◽

...

Keyword(s):

Metal Surface ◽

Room Temperature ◽

Amino Groups ◽

Temperature Activation

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Breaking Simple Scaling Relations through Metal–Oxide Interactions: Understanding Room-Temperature Activation of Methane on M/CeO2 (M = Pt, Ni, or Co) Interfaces

The Journal of Physical Chemistry Letters ◽

10.1021/acs.jpclett.0c02109 ◽

2020 ◽

Vol 11 (21) ◽

pp. 9131-9137

Author(s):

Pablo G. Lustemberg ◽

Feng Zhang ◽

Ramón A. Gutiérrez ◽

Pedro J. Ramírez ◽

Sanjaya D. Senanayake ◽

...

Keyword(s):

Metal Oxide ◽

Room Temperature ◽

Scaling Relations ◽

Simple Scaling ◽

Temperature Activation

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Efficient Room-Temperature Activation of Methane by TaN+ under C−N Coupling

Angewandte Chemie International Edition ◽

10.1002/anie.201606259 ◽

2016 ◽

Vol 55 (38) ◽

pp. 11678-11681 ◽

Cited By ~ 12

Author(s):

Shaodong Zhou ◽

Jilai Li ◽

Maria Schlangen ◽

Helmut Schwarz

Keyword(s):

Room Temperature ◽

Temperature Activation

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Synthesis of a Stable Metallic Niobium Oxide Molecular Sieve and Subsequent Room Temperature Activation of Dinitrogen

Advanced Functional Materials ◽

10.1002/1616-3028(200203)12:3<174::aid-adfm174>3.0.co;2-u ◽

2002 ◽

Vol 12 (3) ◽

pp. 174 ◽

Cited By ~ 17

Author(s):

M. Vettraino ◽

X. He ◽

M. Trudeau ◽

J.E. Drake ◽

D.M. Antonelli

Keyword(s):

Molecular Sieve ◽

Room Temperature ◽

Niobium Oxide ◽

Temperature Activation

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A DFT-Based Analysis of the Grossly Varying Reactivity Pattern in Room-Temperature Activation and Dehydrogenation of CH4by Main-Group Atomic M+(M=Ga, Ge, As, and Se)

Chemistry - A European Journal ◽

10.1002/chem.200901956 ◽

2009 ◽

Vol 15 (43) ◽

pp. 11559-11565 ◽

Cited By ~ 13

Author(s):

Xinhao Zhang ◽

Helmut Schwarz

Keyword(s):

Room Temperature ◽

Main Group ◽

Reactivity Pattern ◽

Temperature Activation

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ChemInform Abstract: Room Temperature Activation of Aryloxysulfonyl Azides by [Co(II)(TPP)] for Selective Radical Aziridination of Alkenes via Metalloradical Catalysis.

ChemInform ◽

10.1002/chin.201538115 ◽

2015 ◽

Vol 46 (38) ◽

pp. no-no

Author(s):

Velusamy Subbarayan ◽

Li-Mei Jin ◽

Xin Cui ◽

X. Peter Zhang

Keyword(s):

Room Temperature ◽

Temperature Activation

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Reactivity Pattern in the Room-Temperature Activation of NH3 by the Main-Group Atomic Ions Ga+, Ge+, As+ and Se+

European Journal of Inorganic Chemistry ◽

10.1002/ejic.200901126 ◽

2010 ◽

Vol 2010 (10) ◽

pp. 1516-1521 ◽

Cited By ~ 16

Author(s):

Gregory K. Koyanagi ◽

Vitaliy Kapishon ◽

Diethard K. Bohme ◽

Xinhao Zhang ◽

Helmut Schwarz

Keyword(s):

Room Temperature ◽

Main Group ◽

Reactivity Pattern ◽

Atomic Ions ◽

Temperature Activation

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Defluorosilylation of trifluoromethane: upgrading an environmentally damaging fluorocarbon

Chemical Communications ◽

10.1039/d0cc04592f ◽

2020 ◽

Vol 56 (85) ◽

pp. 12929-12932

Author(s):

Daniel J. Sheldon ◽

Greg Coates ◽

Mark R. Crimmin

Keyword(s):

Greenhouse Gas ◽

Room Temperature

The rapid, room-temperature defluorosilylation of trifluoromethane, a highly potent greenhouse gas, has been achieved using a simple silyl lithium reagent.

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