Theory of Inhomogeneous Short Range Order and Calphad Modeling. Part 4. Improved Combinatorial Factor
Keyword(s):
An improved combinatorial factor allows to reproduce the correct critical tem-peratures for the Ising lattices.As result, the accuracy of thermodynamic values calculated near the criticalpoint increases by the factor 2 - 3 for the most important lattice types.It is shown why one-particle (Bragg-Williams) and two-particle (Quasichemical)approximations cannot be adequately applied for description of important nuancesof interatomic interaction.The problem of negative entropy values manifested at low temperatures andtypical for model theories is discussed. It is being argued that this problem has tobe treated as exaggerated.
1987 ◽
Vol 45
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pp. 214-215
Keyword(s):
1998 ◽
Vol 08
(PR2)
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pp. Pr2-175-Pr2-178
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