scholarly journals Potential use of quasicrystalline materials as thermal barrier coatings for diesel engine components

2008 ◽  
Author(s):  
M. Brad Beardsley
Author(s):  
P Ramaswamy ◽  
S Seetharamu ◽  
K B R Verma ◽  
N Raman ◽  
K J Rao

8%Y2O3-stabilized zirconia (8YPSZ) and mullite (3Al2O3·2SiO2) powders, which were made plasma sprayable by using an organic binder (polyvinyl alcohol), have been plasma spray coated on to the piston head, valves and cylinder head of a 3.8kW single-cylinder diesel engine, previously coated with Ni-Cr-Al-Y bond coat. The engine with components coated with 250 μm thick 8YPSZ and 1 mm thick mullite thermal barrier coatings has been evaluated for fuel efficiency and for endurance during 500 h long rigorous tests. Improved fuel efficiency was shown by the engine with coated components and the results are discussed. The coatings and the coated components have also been examined for phases, microstructure and chemical composition by X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDAX). Mullite coatings were found to exhibit increased resistance to microcracking compared with 8YPSZ during the 500 h endurance test.


Author(s):  
Anders Thibblin ◽  
Siamak Kianzad ◽  
Stefan Jonsson ◽  
Ulf Olofsson

Thermal barrier coatings have the potential to improve the fuel efficiency of heavy-duty diesel engines by reducing heat losses. A method for in-situ measurement of heat flux from the combustion chamber of a heavy-duty diesel engine has been developed and was used to study the running-in behaviour of different thermal barrier coating materials and types of microstructures. The in-situ measurements show that the initial heat flux was reduced by up to 4.7% for all investigated thermal barrier coatings compared to a steel reference, except for an yttria-stabilized zirconia coating with sealed pores that had an increase of 12.0% in heat flux. Gd2Zr2O7 had the lowest initial value for heat flux. However, running-in shows the lowest values for yttria-stabilized zirconia after 2–3 h. Potential spallation problems were observed for Gd2Zr2O7 and La2Zr2O7.


Author(s):  
M. Kirschner ◽  
T. Wobst ◽  
B. Rittmeister ◽  
Ch. Mundt

One of the major problems facing the users of aircraft engines and stationary gas turbines in dusty and dirty environments is erosion, causing engine performance deterioration. Thermal barrier coatings (TBCs) are often applied on metal engine components as combustor heat shields or tiles as well as turbine blades allowing enhanced operating temperatures and resulting in increased thermal efficiency of the turbine and also reduced fuel consumption and gaseous emission. Erosive attack by airborne dust or fly ash, coarse particles causes coating degradation resulting in lifing issues of engine components. In the present study an erosion test facility was used to simulate the mechanisms of coating degradation expected in gas turbines in a more realistic way closer to real engine conditions. A loading situation combining thermal gradient cycling and erosive media was used. The experiments has been performed with an arc heated plasma wind tunnel (total enthalpy up to 20 MJ/kg), which is available at the Institute for Thermodynamics at the University of the Federal Armed Forces in Munich, Germany. The experimental setup and the integration of the air jet erosion test rig into the existing plasma wind tunnel will be elucidated. Different plasma sprayed thermal barrier coating materials, including the standard TBC material yttria-stabilised zirconia, were investigated regarding their erosion resistance. For validation and verification, samples of nickel-based Mar-M 247 and INCO 718 alloys have been used.


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