Chiral Sulfinyl-Based Olefin Ligands for Rhodium-Catalysed Asymmetric Conjugate Addition of Arylboronic Acids to Cyanoalkenes
2018 ◽
Vol 42
(6)
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pp. 300-304
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A rhodium/sulfinyl-based olefin ligand-catalysed asymmetric conjugate addition of arylboronic acids to cyanoalkenes without activation groups has been developed, where p-tolylsulfinyl-functionalised olefin ligands have been shown to be effective and with moderate enantioselectivities. This is the first example of applying chiral sulfinyl-based olefin ligands in the catalytic asymmetric addition to cyanoalkenes.
2005 ◽
Vol 23
(10)
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pp. 1443-1448
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2005 ◽
Vol 225
(1)
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pp. 33-37
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2007 ◽
Vol 9
(3)
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pp. 407-414
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2000 ◽
Vol 33
(6)
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pp. 346-353
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