Catalytic Asymmetric Addition of Arylboronic Acids to Isatins usingC2-Symmetric CationicN-Heterocyclic Carbenes (NHCs) Pd2+Diaqua Complexes as Catalysts

2011 ◽  
Vol 13 (9) ◽  
pp. 2314-2317 ◽  
Author(s):  
Zhen Liu ◽  
Peng Gu ◽  
Min Shi ◽  
Patrick McDowell ◽  
Guigen Li
Keyword(s):  
Heterocyclic Carbenes ◽  
Asymmetric Addition ◽  
Arylboronic Acids ◽  
Catalytic Asymmetric

scholarly journals Chiral Sulfinyl-Based Olefin Ligands for Rhodium-Catalysed Asymmetric Conjugate Addition of Arylboronic Acids to Cyanoalkenes

2018 ◽  
Vol 42 (6) ◽  
pp. 300-304 ◽  
Author(s):  
Feng Xue ◽  
Yong Zhu ◽  
Xiaolei Qi
Keyword(s):  
Conjugate Addition ◽  
Asymmetric Addition ◽  
Arylboronic Acids ◽  
Catalytic Asymmetric

A rhodium/sulfinyl-based olefin ligand-catalysed asymmetric conjugate addition of arylboronic acids to cyanoalkenes without activation groups has been developed, where p-tolylsulfinyl-functionalised olefin ligands have been shown to be effective and with moderate enantioselectivities. This is the first example of applying chiral sulfinyl-based olefin ligands in the catalytic asymmetric addition to cyanoalkenes.

Synthesis of Solution-Phase Phosphoramidite and Phosphite Ligand Libraries and Their In Situ Screening in the Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids

2007 ◽  
Vol 9 (3) ◽  
pp. 407-414 ◽  
Author(s):  
Richard B. C. Jagt ◽  
Patrick Y. Toullec ◽  
Ebe P. Schudde ◽  
Johannes G. de Vries ◽  
Ben L. Feringa ◽  
...  
Keyword(s):  
Solution Phase ◽  
Asymmetric Addition ◽  
Arylboronic Acids

An efficient catalytic asymmetric addition of trimethylsilyl cyanide to aldehydes at room temperature

2005 ◽  
Vol 46 (13) ◽  
pp. 2223-2226 ◽  
Author(s):  
Zi-Bo Li ◽  
Amaresh R. Rajaram ◽  
Nattawan Decharin ◽  
Ying-Chuan Qin ◽  
Lin Pu
Keyword(s):  
Room Temperature ◽  
Asymmetric Addition ◽  
Trimethylsilyl Cyanide ◽  
Catalytic Asymmetric

Achiral Trisubstituted Thioureas as Secondary Ligands to Cu I Catalysts: Direct Catalytic Asymmetric Addition of α‐Fluoronitriles to Imines

2018 ◽  
Vol 131 (9) ◽  
pp. 2670-2674 ◽  
Author(s):  
Pandur Venkatesan Balaji ◽  
Lennart Brewitz ◽  
Naoya Kumagai ◽  
Masakatsu Shibasaki
Keyword(s):  
Asymmetric Addition ◽  
Catalytic Asymmetric
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