Carbon-Hydrogen Bond Activation of Phenyldi(2- Thienyl)Phosphine at A Triruthenium Cluster Center

Journal of Bangladesh Chemical Society ◽

10.3329/jbcs.v25i1.11764 ◽

2012 ◽

Vol 25 (1) ◽

pp. 1-6 ◽

Author(s):

Shahed Rana ◽

Shishir Ghosh ◽

Shariff E Kabir

Keyword(s):

Hydrogen Bond ◽

Elemental Analysis ◽

Bond Activation ◽

Bond Cleavage ◽

Chemical Society ◽

Cluster Center ◽

Carbon Hydrogen Bond Activation

Ketyl-initiated reaction between Ru3(CO)12 and phenyldi(2-thienyl)phosphine (PhPTh2) furnished simple phosphine-substituted triruthenium clusters [Ru3(CO)10(PhPTh2)21 and [Ru3(CO)9(PhPTh2)3] 2. Heating 1 in boiling benzene afforded [Ru3(CO)8{?3- PhThP(C4H2S)}(PhPTh2)] 3 by carbon-hydrogen bond cleavage of a coordinated thienylphosphine ligand. All three new clusters have been characterized by elemental analysis, IR and NMR spectroscopic data.DOI: http://dx.doi.org/10.3329/jbcs.v25i1.11764 Journal of Bangladesh Chemical Society, Vol. 25(1), 1-6, 2012

Download Full-text

Pd‐Au Supported Reduced Graphene Oxide Catalyst for Carbon‐ Hydrogen Bond Activation in Benzene

ChemistrySelect ◽

10.1002/slct.202101988 ◽

2021 ◽

Vol 6 (28) ◽

pp. 7111-7117

Author(s):

Deepika Sharma ◽

Kamal Kishor Thakur ◽

Neeraj Gupta

Keyword(s):

Hydrogen Bond ◽

Graphene Oxide ◽

Reduced Graphene Oxide ◽

Oxide Catalyst ◽

Bond Activation ◽

Reduced Graphene ◽

Carbon Hydrogen Bond Activation

Download Full-text

Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes

Organometallics ◽

10.1021/om990255p ◽

1999 ◽

Vol 18 (14) ◽

pp. 2707-2717 ◽

Author(s):

Peter J. Alaimo ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

Download Full-text

Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of CpIr(L)(oxalate) and CpIr(L)(N3)2 complexes

Inorganic Chemistry ◽

10.1021/ic00004a043 ◽

1991 ◽

Vol 30 (4) ◽

pp. 836-840 ◽

Author(s):

Daniel A. Freedman ◽

Kent R. Mann

Keyword(s):

Hydrogen Bond ◽

Transition Metal ◽

Bond Activation ◽

Photochemical Generation ◽

Near Ultraviolet ◽

Carbon Hydrogen Bond Activation ◽

Ultraviolet Photolysis

Download Full-text

Carbon-hydrogen bond activation using a bis(phosphine)iridium carbonyl hydride and the carbonylation of benzene

Organometallics ◽

10.1021/om00078a013 ◽

1983 ◽

Vol 2 (6) ◽

pp. 764-767 ◽

Author(s):

Barbara J. Fisher ◽

Richard Eisenberg

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

Download Full-text

Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition

10.1016/j.poly.2004.09.005 ◽

2004 ◽

Vol 23 (17) ◽

pp. 2943-2954 ◽

Author(s):

Britton K. Corkey ◽

Felicia L. Taw ◽

Robert G. Bergman ◽

Maurice Brookhart

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Oxidative Addition ◽

Substituent Effects ◽

Carbon Hydrogen Bond Activation

Download Full-text

Cationic η2-arene complexes of rhenium in carbon-hydrogen bond activation

Journal of the American Chemical Society ◽

10.1021/ja00340a033 ◽

1983 ◽

Vol 105 (2) ◽

pp. 305-306 ◽

Author(s):

James R. Sweet ◽

William A. G. Graham

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Arene Complexes ◽

Carbon Hydrogen Bond Activation

Download Full-text

Orthometallation in iridium N-heterocycle stabilized carbene complexes via carbon halogen and carbon hydrogen bond activation induced by silver nanoparticles

Inorganica Chimica Acta ◽

10.1016/j.ica.2018.10.016 ◽

2019 ◽

Vol 486 ◽

pp. 1-7 ◽

Author(s):

Andrew C. Marr ◽

Graham C. Saunders ◽

Hayden P. Thomas ◽

Yue-Ming Wang

Keyword(s):

Hydrogen Bond ◽

Silver Nanoparticles ◽

Bond Activation ◽

Carbene Complexes ◽

Carbon Hydrogen Bond Activation

Download Full-text

New cationic bis(.eta.3-allyl)ruthenium(IV) complexes from allylic carbon-hydrogen bond activation of alkenes

Organometallics ◽

10.1021/om00031a050 ◽

1993 ◽

Vol 12 (7) ◽

pp. 2752-2756 ◽

Author(s):

Kenji Itoh ◽

Katsuyuki Masuda ◽

Hideaki Ikeda

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

Download Full-text

ChemInform Abstract: THE MECHANISM AND THERMODYNAMICS OF ALKANE AND ARENE CARBON-HYDROGEN BOND ACTIVATION IN (C5ME5)RH(PME3)(R)H

Chemischer Informationsdienst ◽

10.1002/chin.198426311 ◽

1984 ◽

Vol 15 (26) ◽

Author(s):

W. D. JONES ◽

F. J. FEHER

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

Download Full-text

Photochemical carbon-hydrogen bond activation of coordinated propene in (.eta.5-C5Me5)Re(CO)2(.eta.2-C3H6). X-ray structure determination of exo and endo isomers of the resulting .eta.3-allyl(hydrido) complex (.eta.5-C5Me5)Re(H)(CO)(.eta.3-C3H5)

Journal of the American Chemical Society ◽

10.1021/ja00191a074 ◽

1989 ◽

Vol 111 (9) ◽

pp. 3468-3469 ◽

Author(s):

Raymond J. Batchelor ◽

Frederick W. B. Einstein ◽

Richard H. Jones ◽

Jun Ming Zhuang ◽

Derek Sutton

Keyword(s):

Hydrogen Bond ◽

Structure Determination ◽

Bond Activation ◽

X Ray ◽

Carbon Hydrogen Bond Activation

Download Full-text