scholarly journals Photoelectron Circular Dichroism as a Probe of Chiral Hydrocarbons

Chemistry ◽  
2022 ◽  
Vol 4 (1) ◽  
pp. 31-41
Author(s):  
Piero Decleva

The sensitivity of Photoelectron Circular Dichroism (PECD) in the angular distribution of photoelectrons, a recent chiral technique, to detect chirality in pure hydrocarbons is investigated in a number of benchmark molecules. It is found that a very large chiral signal is expected, surpassing most current examples, giving a sure fingerprint of absolute configuration. On the other hand, the sensitivity to specific isomers or closely related molecules is relatively modest.

2021 ◽  
Author(s):  
Kun Won Lee ◽  
Ahmed H. E. Hassan ◽  
Youngdo Jeong ◽  
Seolmin Yoon ◽  
Seung-Hwan Kim ◽  
...  

Enantioseparation and assignment of absolute configuration of methoxetamine (MXE) enantiopure stereoisomers; a promising novel antidepressant for management of treatment-resistant depression.


1993 ◽  
Vol 48 (2) ◽  
pp. 140-148 ◽  
Author(s):  
J. Fleischhauer ◽  
A. Koslowski ◽  
B. Kramer ◽  
E. Zobel ◽  
G. Bringmann ◽  
...  

AbstractThe circular dichroism (CD) of the biaryls ancistrocladeine and dioncophylleine A has been studied. The CNDO/S method in combination with a Boltzmann weighting o f different structures using AM 1 energies has been applied to reproduce the experimental CD spectra o f the two alkaloids with known absolute configuration at with those o f the exciton chirality method.


Chirality ◽  
2009 ◽  
pp. NA-NA ◽  
Author(s):  
Antje Bodensieck ◽  
Walter M.F. Fabian ◽  
Olaf Kunert ◽  
Ferdinand Belaj ◽  
Sajid Jahangir ◽  
...  

Heterocycles ◽  
2012 ◽  
Vol 85 (8) ◽  
pp. 1961 ◽  
Author(s):  
Pedro Joseph-Nathan ◽  
Marcelo A. Muñoz ◽  
Carlos Areche ◽  
Juana Rovirosa ◽  
Aurelio San Martín ◽  
...  

1976 ◽  
Vol 5 (4) ◽  
pp. 363-366 ◽  
Author(s):  
Masaru Moriyama ◽  
Kaoru Kuriyama ◽  
Tatsuo Iwata ◽  
Naomichi Furukawa ◽  
Tatsuo Numata ◽  
...  

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