scholarly journals On the Schrödinger Equation for Time-Dependent Hamiltonians with a Constant Form Domain

Mathematics ◽  
2022 ◽  
Vol 10 (2) ◽  
pp. 218
Author(s):  
Aitor Balmaseda ◽  
Davide Lonigro ◽  
Juan Manuel Pérez-Pardo

We study two seminal approaches, developed by B. Simon and J. Kisyński, to the well-posedness of the Schrödinger equation with a time-dependent Hamiltonian. In both cases, the Hamiltonian is assumed to be semibounded from below and to have a constant form domain, but a possibly non-constant operator domain. The problem is addressed in the abstract setting, without assuming any specific functional expression for the Hamiltonian. The connection between the two approaches is the relation between sesquilinear forms and the bounded linear operators representing them. We provide a characterisation of the continuity and differentiability properties of form-valued and operator-valued functions, which enables an extensive comparison between the two approaches and their technical assumptions.

Author(s):  
Niels Engholm Henriksen ◽  
Flemming Yssing Hansen

This introductory chapter considers first the relation between molecular reaction dynamics and the major branches of physical chemistry. The concept of elementary chemical reactions at the quantized state-to-state level is discussed. The theoretical description of these reactions based on the time-dependent Schrödinger equation and the Born–Oppenheimer approximation is introduced and the resulting time-dependent Schrödinger equation describing the nuclear dynamics is discussed. The chapter concludes with a brief discussion of matter at thermal equilibrium, focusing at the Boltzmann distribution. Thus, the Boltzmann distribution for vibrational, rotational, and translational degrees of freedom is discussed and illustrated.


1979 ◽  
Vol 43 (7) ◽  
pp. 512-515 ◽  
Author(s):  
Vida Maruhn-Rezwani ◽  
Norbert Grün ◽  
Werner Scheid

1999 ◽  
Vol 40 (7) ◽  
pp. 3268-3274 ◽  
Author(s):  
Federico Finkel ◽  
Artemio González-López ◽  
Niky Kamran ◽  
Miguel A. Rodrı́guez

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