The color of 15 red wines from several wineries within the renowned wine-producing region Rioja (Northern Spain) was measured by spectrophotometric and spectroradiometric techniques and was visually assessed in a pair-comparison experiment by a panel of 10 experienced observers having normal color vision. Correlation between instrumental color measurements made by spectrophotometric and spectroradiometric techniques was very low, as expected from major differences in the experimental conditions employed (different illumination, path lengths and glass effects). Spectroradiometric measurements at the center of the wine sampler and at positions displaced 1 cm in the horizontal and vertical directions were quite different, mainly because of an increase of the lightness L*, the average color differences between them being high (3.5 and 2.6 CIELAB units, respectively). A 50% acceptance percentage resulted for a color difference of 2.8 CIELAB units, using a reference anchor-pair of wine samples with 4.0 CIELAB units. Thus, a value around 3.0 CIELAB units should be considered a preliminary estimate of the acceptable tolerance by the human eye for red wines poured in standard wine samplers.
