scholarly journals Supplementary material to "<i>In situ</i> nuclear magnetic resonance response of permafrost and active layer soil in boreal and tundra ecosystems"

Author(s):  
M. Andy Kass ◽  
Trevor P. Irons ◽  
Burke J. Minsley ◽  
Neal J. Pastick ◽  
Dana R. N. Brown ◽  
...  
1968 ◽  
Vol 46 (1) ◽  
pp. 74-74 ◽  
Author(s):  
J. B. Hyne ◽  
A. R. Fabris

Tetra-n-butylammonium salts effect the nuclear magnetic resonance response of the para and meta protons of nitrobenzene to a greater extent than that of the ortho protons in solutions in carbon tetra chloride. It is suggested that this effect may be due to a specific interaction between the salt, in ion-pair form, and the aromatic ring of nitrobenzene.


2015 ◽  
Vol 18 (03) ◽  
pp. 400-406 ◽  
Author(s):  
A.. Tinni ◽  
E.. Odusina ◽  
I.. Sulucarnain ◽  
C.. Sondergeld ◽  
C. S. Rai

Summary The application of nuclear-magnetic-resonance (NMR) methods to evaluate the fluid content in hydrocarbon reservoirs requires the understanding of the NMR response of the fluids present in the rock. The presence of multiple fluids such as liquid, gaseous, or adsorbed phases in nanometer-sized pores (associated with various minerals and organic matter) adds another degree of complexity to the interpretation of NMR data in shales. We present a laboratory study on the NMR responses of brine, oil, and methane in shales at 2 MHz. NMR transverse relaxation time (T2) distributions were acquired on core plugs from the Haynesville, Barnett, and Woodford shale formations. The NMR T2 distributions were acquired after brine (2.5% potassium chloride) and oil (dodecane) imbibition and saturation. After brine imbibition, we observed an increase in porosity at T2 ≤ 1 ms. However, after saturation at increasing pressures we observe a porosity increase at T2 ≈ 6–20 ms. Dodecane imbibition and saturation induced a porosity increase at T2 ≈ 10 ms. The measurements with methane were conducted on Haynesville core plugs at a methane pressure of 4,000 psi. The NMR T2 signal of methane in shales appears to be at approximately 10 ms. These results show that the NMR response of methane and oil is very similar in shales. Monitoring the saturation increase with NMR shows that brine can enter the entire pore spectrum, whereas oil and methane have access only to a fraction of the pore space.


2017 ◽  
Author(s):  
M. Andy Kass ◽  
Trevor P. Irons ◽  
Burke J. Minsley ◽  
Neal J. Pastick ◽  
Dana R. N. Brown ◽  
...  

Abstract. Characterization of permafrost, particularly warm and near-surface permafrost which can contain significant liquid water, is critical to understanding complex interrelationships with climate change, ecosystems, and disturbances such as wildfires. Understanding the vulnerability and resilience of permafrost requires an interdisciplinary approach, relying on (for example) geophysical investigations, ecological characterization, direct observations, remote sensing, and more. As part of a multi-year investigation into the impacts of wildfires to permafrost, we have collected in situ measurements of the nuclear magnetic resonance (NMR) response of active layer and permafrost in a variety of soil conditions, types, and saturations. In this paper, we summarize the NMR data and present quantitative relationships between active layer and permafrost liquid water content and pore sizes. Through statistical analyses and synthetic freezing simulations, we also demonstrate that borehole NMR can image the nucleation of ice within soil pore spaces.


2017 ◽  
Vol 11 (6) ◽  
pp. 2943-2955 ◽  
Author(s):  
M. Andy Kass ◽  
Trevor P. Irons ◽  
Burke J. Minsley ◽  
Neal J. Pastick ◽  
Dana R. N. Brown ◽  
...  

Abstract. Characterization of permafrost, particularly warm and near-surface permafrost which can contain significant liquid water, is critical to understanding complex interrelationships with climate change, ecosystems, and disturbances such as wildfires. Understanding the vulnerability and resilience of permafrost requires an interdisciplinary approach, relying on (for example) geophysical investigations, ecological characterization, direct observations, remote sensing, and more. As part of a multiyear investigation into the impacts of wildfires on permafrost, we have collected in situ measurements of the nuclear magnetic resonance (NMR) response of the active layer and permafrost in a variety of soil conditions, types, and saturations. In this paper, we summarize the NMR data and present quantitative relationships between active layer and permafrost liquid water content and pore sizes and show the efficacy of borehole NMR (bNMR) to permafrost studies. Through statistical analyses and synthetic freezing simulations, we also demonstrate that borehole NMR is sensitive to the nucleation of ice within soil pore spaces.


2001 ◽  
Vol 28 (11) ◽  
pp. 2370-2378 ◽  
Author(s):  
Vaclav Spevacek ◽  
Josef Novotny ◽  
Pavel Dvorak ◽  
Josef Novotny ◽  
Josef Vymazal ◽  
...  

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