scholarly journals CATALYTIC SYN TIC SYNTHESIS OF PYRIDINES BASED ON THE CRO THESIS OF PYRIDINES BASED ON THE CROTON FRACTION

2020 ◽  
Vol 4 (5) ◽  
pp. 34-40
Author(s):  
Husan Shomurodovich Tilavov ◽  
◽  
Hasan Irgashevich Kadirov

Background. The presence in the molecule of pyridine bases of nitrogen atoms having the properties of the bases determines the specificity of the products of this class and gives ample opportunities for their use in various industries. . The chemistry of pyridine bases is associated with such general theoretical issues as the electronic structure of the cycle, aromaticity, the effect of substituents on the reactivity of heterocycles in nucleophilic substitution reactions, and tautomerism. At the same time, systematic data on the reactions of alkylation with dihalo-alkanes, acylation under low-temperature poly-condensation, and complexation were not available to create a complete picture of the reactivity of pyridine bases. Materials and methods. The aim of the work is to develop cheap and convenient methods for the preparation of pyridine bases, to search for effective and selective process catalysts, and to determine the degree of anticorrosion protection of metals of the obtained products.

1978 ◽  
Vol 39 (C6) ◽  
pp. C6-416-C6-417
Author(s):  
B. M. Klein ◽  
L. L. Boyer ◽  
D. A. Papaconstantopoulos

2017 ◽  
Vol 4 (9) ◽  
pp. 094001
Author(s):  
G Krishnamurthy Grandhi ◽  
Renu Tomar ◽  
Ranjani Viswanatha

Author(s):  
Nikolay G. Maksimov ◽  
Victor V. Verpekin ◽  
Dmitry V. Zimonin ◽  
Galina V. Burmakina ◽  
Oleg S. Chudin ◽  
...  

The chemical oxidation of the cluster CpReFePt(μ3-C=CHPh)(CO)5(dppe) (Cp = η5-C5H5, dppe = η2- Ph2P(CH2)2PPh2) resulted in a radical cation [CpReFePt(μ3-C=CHPh)(CO)5(dppe)]+• that is sufficiently stable only at low temperature. An electronic structure of the radical cation was studied by EPR and following parameters were obtained by comparison of the experimental and model spectrum: gx = 2.070 gy = 2.0295 gz = 1.997; Ax(31P) = 17 Ay(31P) = 49 Az(31P) = 35 (Gs);Ax(195Pt) = 62 Ay(195Pt) = 45 Az(195Pt) = 105 (Gs). An unpaired electron is seen to be mainly concentrated on the iron atom (85-90%) and partially on the platinum atom (10-15%). Further transformation of the radical cation led to the formation of the binuclear complex Cp(CO)2RePt(μ-C=CHPh)(dppe) and the Fe-carbonyl fragment


1984 ◽  
Vol 57 (5-6) ◽  
pp. 629-649 ◽  
Author(s):  
M. Dacorogna ◽  
T. Jarlborg ◽  
A. Junod ◽  
M. Pelizzone ◽  
M. Peter

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 52048-52057 ◽  
Author(s):  
J.-B. Vaney ◽  
J.-C. Crivello ◽  
C. Morin ◽  
G. Delaizir ◽  
J. Carreaud ◽  
...  

The first-order lattice distortion undergone by β-As2Te3 around 200 K results in a cycling effect on its transport properties.


2000 ◽  
Vol 62 (12) ◽  
pp. 8082-8086 ◽  
Author(s):  
R. I. G. Uhrberg ◽  
H. M. Zhang ◽  
T. Balasubramanian ◽  
S. T. Jemander ◽  
N. Lin ◽  
...  

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