Assembly of 1,2,3,4-Benzenetetracarboxylic Acid and Zinc(II) Metal Centers to a Chiral 3D Metal-organic Framework: Syntheses, Structure and Properties

2011 ◽  
Vol 66 ◽  
pp. 0533 ◽  
Author(s):  
C. Ji ◽  
S.-Q. Zang ◽  
J.-Y. Liu ◽  
J.-B. Li ◽  
H.-W. Hou
Keyword(s):  
Metal Organic Framework ◽  
Structure And Properties ◽  
Metal Centers ◽  
Metal Organic ◽  
Organic Framework

Synthesis, structure and properties of a high-energy metal−organic framework fuel [Cu(MTZ)2(CTB)2]n

2022 ◽  
Author(s):  
Hao-Zheng Mei ◽  
Yiqiang Xu ◽  
Guorong Lei ◽  
Wenli Cao ◽  
Zhimin Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Energy ◽  
Structure And Properties ◽  
Metal Centers ◽  
Metal Organic ◽  
Organic Framework

In this study, a novel high-energy metal-organic framework (MOF, [Cu(MTZ)2(CTB)2]n) was constructed based on the nitrogen-rich cyanotetrazolylborohydride (CTB) and 1-methyltriazole (MTZ) ligands, with Cu2+ as the autocatalytic metal centers. The...

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

scholarly journals Enhancing the stability and porosity of penetrated metal–organic frameworks through the insertion of coordination sites

2018 ◽  
Vol 9 (4) ◽  
pp. 950-955 ◽  
Author(s):  
Rui Feng ◽  
Yan-Yuan Jia ◽  
Zhao-Yang Li ◽  
Ze Chang ◽  
Xian-He Bu
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Structure And Properties ◽  
Coordination Sites ◽  
Metal Organic ◽  
The Stability ◽  
Enhanced Stability ◽  
Organic Framework

Guided by the insertion of coordination sites within ligands, an interpenetrated metal–organic framework (MOFs) NKU-112 and a self-penetrated framework NKU-113 were obtained. The enhanced stability and porosity of NKU-113 prove the efficiency of the method for the structure and properties modulation of penetrated MOFs.

Syntheses, Structure, and Properties of a Novel Cobalt Metal-Organic Framework

2020 ◽  
Vol 90 (12) ◽  
pp. 2365-2370
Author(s):  
H. X. Kang ◽  
Y. Q. Fu ◽  
L. Y. Xin ◽  
M. Jiu ◽  
L. J. Wang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Cobalt Metal ◽  
Structure And Properties ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields

RSC Advances ◽  
2018 ◽  
Vol 8 (25) ◽  
pp. 13675-13678 ◽  
Author(s):  
Lin Hu ◽  
Zhe Wang ◽  
Hui Wang ◽  
Zhe Qu ◽  
Qianwang Chen
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
High Magnetic Field ◽  
Metal Organic Framework ◽  
High Magnetic Fields ◽  
Structure And Properties ◽  
Metal Organic ◽  
Organic Framework

High magnetic field-induced synthesis has been demonstrated to tune the structure and properties of the multiferroic metal–organic framework [(CH3)2NH2][Mn(HCOO)3].

Synthesis, Structure, and Properties of New Mg(II)-Metal–Organic Framework and Its Prowess as Catalyst in the Production of 4H-Pyrans

2017 ◽  
Vol 56 (11) ◽  
pp. 2917-2924 ◽  
Author(s):  
Kranthi Kumar Gangu ◽  
Suresh Maddila ◽  
Saratchandra Babu Mukkamala ◽  
Sreekantha B Jonnalagadda
Keyword(s):  
Metal Organic Framework ◽  
Structure And Properties ◽  
Metal Organic ◽  
Organic Framework
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