scholarly journals Thermodynamic Properties of FeCl3-graphite Intercalation Compounds by Mass-spectrometric Knudsen Effusion Method

TANSO ◽  
1996 ◽  
Vol 1996 (175) ◽  
pp. 266-271
Author(s):  
Yumi Osa ◽  
Takeshi Abe ◽  
Yasuo Mizutani ◽  
Mitsuru Asano
Keyword(s):  
Thermodynamic Properties ◽  
Mass Spectrometric ◽  
Intercalation Compounds ◽  
Graphite Intercalation Compounds ◽  
Knudsen Effusion ◽  
Graphite Intercalation ◽  
Knudsen Effusion Method ◽  
Effusion Method

Vapor pressure measurements and thermodynamics of some volatile phthalocyanines

2006 ◽  
Vol 10 (08) ◽  
pp. 1034-1039 ◽  
Author(s):  
Petr Semyannikov ◽  
Tamara Basova ◽  
Sergei Trubin ◽  
Evgeny Kol'tsov ◽  
Igor Igumenov
Keyword(s):  
Thermal Decomposition ◽  
Vapor Pressure ◽  
Gaseous Phase ◽  
Mass Spectrometric ◽  
Pressure Measurements ◽  
Knudsen Effusion ◽  
Solid Compounds ◽  
Knudsen Effusion Method ◽  
Vapor Pressure Measurements ◽  
Effusion Method

Mass spectrometric studies of the composition of the gaseous phase for solid compounds of hexadecafluorinated phthalocyanines MPcF 16, M = Cu , Zn , VO and their unsubstituted MPc analogs were performed in a temperature range up to 600°C. It has been shown that phthalocyanines sublime into the form of monomers without thermal decomposition. The vapor pressure of these phthalocyanines was determined as a function of temperature by the Knudsen effusion method, in which the rate of effusion of the equilibrium vapor through a small orifice was measured. The thermodynamic parameters of the sublimation process for phthalocyanines were calculated.

Dissociation Energy of the SbPb Moleculc from Mass Spectrometric High Temperature Studies

1981 ◽  
Vol 36 (8) ◽  
pp. 913-916 ◽  
Author(s):  
K. F. Zmbov ◽  
A. Neubert ◽  
H. R. Ihle
Keyword(s):  
High Temperature ◽  
Dissociation Energy ◽  
Diatomic Molecules ◽  
Mass Spectrometric ◽  
Group V ◽  
Knudsen Effusion ◽  
Knudsen Effusion Method ◽  
Effusion Method

Abstract The observation of the gaseous BiPb molecule [1,2] suggests the existence of heteronuclear diatomic molecules of lead with the group V-b elements. The present paper reports on the identification of the SbPb(g) molecule and the determination of its dissociation energy by mass spectrometric Knudsen-effusion method.

Vapour pressure of some phthalocyanines

2000 ◽  
Vol 04 (03) ◽  
pp. 271-277 ◽  
Author(s):  
P. P. SEMYANNIKOV ◽  
T. V. BASOVA ◽  
V. M. GRANKIN ◽  
I. K. IGUMENOV
Keyword(s):  
Thermal Decomposition ◽  
Thermodynamic Parameters ◽  
Gaseous Phase ◽  
Vapour Pressure ◽  
Mass Spectrometric ◽  
Knudsen Effusion ◽  
Sublimation Process ◽  
Solid Compounds ◽  
Knudsen Effusion Method ◽  
Effusion Method

Mass spectrometric studies of the composition of the gaseous phase under solid compounds of free phthalocyanine ( H 2 Pc ) and its complexes with aluminium ( AlClPc , AlFPc , ( AlPc )2 O ) and copper ( CuPc ) were performed in the temperature range up to 700 °C. It has been shown that the phthalocyanines sublime in the form of monomers, excluding one aluminium complex. All phthalocyanines under investigation sublime without thermal decomposition until 700 °C. The vapour pressure of these phthalocyanines was determined as a function of temperature by the Knudsen effusion method, in which the rate of effusion of the equilibrium vapour through a small orifice was measured. The thermodynamic parameters of the sublimation process for phthalocyanies were calculated.

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