chiral enolates
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scholarly journals Trapping of chiral enolates generated by Lewis acid promoted conjugate addition of Grignard reagents to unreactive Michael acceptors by various electrophiles

2019 ◽  
Vol 55 (78) ◽  
pp. 11766-11769
Author(s):  
Denisa Vargová ◽  
Juana M. Pérez ◽  
Syuzanna R. Harutyunyan ◽  
Radovan Šebesta
Keyword(s):  
Carboxylic Acids ◽  
Lewis Acid ◽  
Conjugate Addition ◽  
Grignard Reagents ◽  
Michael Acceptors ◽  
Chiral Enolates

Chiral enolates generated by asymmetric Cu-catalyzed and Lewis acid promoted conjugate addition of Grignard reagents to unsaturated amides, alkenylheterocycles, and carboxylic acids are trapped with cations, activated alkenes, or bromine.

ChemInform Abstract: Asymmetric Synthesis of Multisubstituted Dihydrobenzofurans by Intramolecular Conjugate Addition of Short-Lived C-O Axially Chiral Enolates.

ChemInform ◽  
2016 ◽  
Vol 47 (46) ◽  
Author(s):  
Keisuke Tomohara ◽  
Koji Kasamatsu ◽  
Tomoyuki Yoshimura ◽  
Takumi Furuta ◽  
Takeo Kawabata
Keyword(s):  
Asymmetric Synthesis ◽  
Conjugate Addition ◽  
Axially Chiral ◽  
Chiral Enolates

ChemInform Abstract: Asymmetric Catalysis with Ethylene. Synthesis of Functionalized Chiral Enolates.

ChemInform ◽  
2016 ◽  
Vol 47 (21) ◽  
Author(s):  
Souvagya Biswas ◽  
Jordan P. Page ◽  
Kendra R. Dewese ◽  
T. V. RajanBabu
Keyword(s):  
Asymmetric Catalysis ◽  
Ethylene Synthesis ◽  
Chiral Enolates

scholarly journals Asymmetric Synthesis of Multisubstituted Dihydrobenzofurans by Intramolecular Conjugate Addition of Short-Lived C–O Axially Chiral Enolates

2016 ◽  
Vol 64 (7) ◽  
pp. 899-906 ◽  
Author(s):  
Keisuke Tomohara ◽  
Koji Kasamatsu ◽  
Tomoyuki Yoshimura ◽  
Takumi Furuta ◽  
Takeo Kawabata
Keyword(s):  
Asymmetric Synthesis ◽  
Conjugate Addition ◽  
Axially Chiral ◽  
Chiral Enolates

scholarly journals Asymmetric Catalysis with Ethylene. Synthesis of Functionalized Chiral Enolates

2015 ◽  
Vol 137 (45) ◽  
pp. 14268-14271 ◽  
Author(s):  
Souvagya Biswas ◽  
Jordan P. Page ◽  
Kendra R. Dewese ◽  
T. V. RajanBabu
Keyword(s):  
Asymmetric Catalysis ◽  
Ethylene Synthesis ◽  
Chiral Enolates

Asymmetric Induction via Short-Lived Chiral Enolates with a Chiral C–O Axis

2013 ◽  
Vol 135 (19) ◽  
pp. 7102-7105 ◽  
Author(s):  
Tomoyuki Yoshimura ◽  
Keisuke Tomohara ◽  
Takeo Kawabata
Keyword(s):  
Asymmetric Induction ◽  
Chiral Enolates

ChemInform Abstract: Asymmetric Intramolecular Conjugate Addition of α-Amino Acid Derivatives via Racemization-Free Equilibrium of Intermediary Chiral Enolates.

ChemInform ◽  
2013 ◽  
Vol 44 (18) ◽  
pp. no-no
Author(s):  
Daiki Monguchi ◽  
Tomoyuki Yoshimura ◽  
Kazuyuki Irie ◽  
Kazuhiro Hayashi ◽  
Swapan Majumdar ◽  
...  
Keyword(s):  
Amino Acid ◽  
Conjugate Addition ◽  
Amino Acid Derivatives ◽  
Chiral Enolates
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