Quadrupole Moments of the 40Ca Core Plus One Nucleon Nuclei 41Sc and 41Ca

The electric-field-gradient (EFG) and anisotropic chemical shift of 45Sc(Iπ = 7/2- , stable) in TiO2 crystal were determined by detecting the FT-NMR of 45Sc(0.5 atm% of Ti in TiO2) doped in TiO2 crystal at a high field of 7.0 T and 9.4 T. Using the EFG, an old β-NQR spectrum of 41Sc was reanalyzed to obtain (41Sc)/ which was combined with the renewed (45Sc) = -(23.6 0.2) fm2 to obtain (41Sc; Iπ= 7/2- , T1/2 = 0.596 s) = (15.6±0.3) fm2. Also the atomic EFG in Ca was recalculated, using a finite-element multi configuration Hartree-Fock method to renew Q(43Ca). Finally using the known hyperfine constants of 41Ca, the (41Ca) value has been renewed