<p>Frost diagrams provide
convenient illustrations of the aqueous reduction potentials and thermodynamic
tendencies of different oxidation states of an element. Undergraduate textbooks
often describe the lowest point on a Frost diagram as the most stable oxidation
state of the element, but this interpretation is incorrect because the
thermodynamic stability of each oxidation state depends on the specific redox
conditions in solution (i.e., the potential applied by the environment or an
electrode). Further confusion is caused by the widespread use of different,
contradictory conventions for labeling the y-axis of these diagrams as either n<i>E</i>°
or −n<i>E</i>°, among other possibilities. To aid in discussing and correcting
these common mistakes, we introduce a series of interactive Frost diagrams that
illustrate the conditional dependence of the relative stabilities of each
oxidation state of an element. We include instructor’s notes for using these interactive
diagrams and a written activity for students to complete using these diagrams.</p>