degenerative chain transfer
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scholarly journals Alcohol mediated degenerate chain transfer controlled cationic polymerisation of para-alkoxystyrene

2019 ◽  
Vol 10 (30) ◽  
pp. 4126-4133 ◽  
Author(s):  
Alka Prasher ◽  
Huamin Hu ◽  
Joji Tanaka ◽  
David A. Nicewicz ◽  
Wei You
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Triflic Acid ◽  
Cationic Polymerisation ◽  
Degenerative Chain Transfer

In this report we demonstrate methanol as an effective degenerative chain transfer agent to control the cationic polymerisation (initiated by triflic acid) of electron rich p-alkoxy-styrenes, such as p-methoxystyrene (p-MOS).

Degenerative Chain Transfer

2016 ◽  
Author(s):  
Stanisław Penczek ◽  
Graeme Moad
Keyword(s):  
Chain Transfer ◽  
Degenerative Chain Transfer

A novel method for the measurement of degenerative chain transfer coefficients: proof of concept and experimental validation

2016 ◽  
Vol 7 (19) ◽  
pp. 3334-3349 ◽  
Author(s):  
Pieter Derboven ◽  
Paul H. M. Van Steenberge ◽  
Marie-Françoise Reyniers ◽  
Christopher Barner-Kowollik ◽  
Dagmar R. D'hooge ◽  
...  
Keyword(s):  
Experimental Validation ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Proof Of Concept ◽  
Transfer Coefficients ◽  
Reversible Addition ◽  
Novel Method ◽  
Degenerative Chain Transfer

A novel method is presented to determine transfer coefficients in degenerative reversible addition fragmentation chain transfer (RAFT) polymerization from experimental dispersity data.

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