scholarly journals Solid Superbase‐Catalyzed Stereoselective 1,4‐Addition Reactions of Simple Amides in Batch and Continuous‐Flow Systems

2019 ◽  
Vol 361 (16) ◽  
pp. 3807-3812 ◽  
Author(s):  
Parijat Borah ◽  
Yasuhiro Yamashita ◽  
Shū Kobayashi
Author(s):  
K Dixon

The Broughton equation for carryover constant k contains an assumption. It is shown that a slightly different equation can be derived in which there are no assumptions. A procedure is described whereby knowledge of the carryover constant k can be used to correct analytical results in computer-controlled instruments. In a commercial instrument, use of the wrong correction algorithm can lead to errors of 10% in the carryover correction.


Tetrahedron ◽  
2018 ◽  
Vol 74 (25) ◽  
pp. 3176-3182 ◽  
Author(s):  
Sarah M. Hunter ◽  
Flavien Susanne ◽  
Robert Whitten ◽  
Thoralf Hartwig ◽  
Mark Schilling

Author(s):  
Alexander Steiner ◽  
Oscar de Frutos ◽  
Juan A. Rincón ◽  
Carlos Mateos ◽  
Jason Williams ◽  
...  

N-Chloroamines have recently seen interest as substrates for atom-transfer radical addition (ATRA) reactions with olefins, to form β-chloroamine products, with complete atom incorporation. We report the development of a fully...


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