The Mechanism of Oxidation of Allylic Alcohols to α,β-Unsaturated Ketones by Cytochrome P450†

1996 ◽  
Vol 9 (5) ◽  
pp. 871-874 ◽  
Author(s):  
Giuseppe Bellucci ◽  
Cinzia Chiappe ◽  
Laura Pucci ◽  
Pier Giovanni Gervasi
Keyword(s):  
Cytochrome P450 ◽  
Allylic Alcohols ◽  
Unsaturated Ketones ◽  
Mechanism Of Oxidation

Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones

2015 ◽  
Vol 51 (57) ◽  
pp. 11512-11514 ◽  
Author(s):  
Shu-Jie Chen ◽  
Guo-Ping Lu ◽  
Chun Cai
Keyword(s):  
Allylic Alcohols ◽  
Unsaturated Ketones ◽  
Efficient Construction ◽  
Decarboxylative Allylation

A highly regioselective protocol is reported for the efficient construction of γ,δ-unsaturated ketones from β-ketoacids and allylic alcohols.

Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts.

ChemInform ◽  
2003 ◽  
Vol 34 (15) ◽  
Author(s):  
Mario De bruyn ◽  
Dirk E. De Vos ◽  
Pierre A. Jacobs
Keyword(s):  
Hydrogen Transfer ◽  
Allylic Alcohols ◽  
Unsaturated Ketones

Chemoselective Reduction of Complexα,β-Unsaturated Ketones to Allylic Alcohols over Ir-Metal Particles onβ Zeolites

2003 ◽  
Vol 42 (43) ◽  
pp. 5333-5336 ◽  
Author(s):  
Mario De bruyn ◽  
Simona Coman ◽  
Roxana Bota ◽  
Vasile I. Parvulescu ◽  
Dirk E. De Vos ◽  
...  
Keyword(s):  
Metal Particles ◽  
Allylic Alcohols ◽  
Unsaturated Ketones

Role of the conserved threonine 309 in mechanism of oxidation by cytochrome P450 2D6

2005 ◽  
Vol 338 (2) ◽  
pp. 1065-1074 ◽  
Author(s):  
Peter H.J. Keizers ◽  
Loek H.M. Schraven ◽  
Chris de Graaf ◽  
Mats Hidestrand ◽  
Magnus Ingelman-Sundberg ◽  
...  
Keyword(s):  
Cytochrome P450 ◽  
Cytochrome P450 2D6 ◽  
Mechanism Of Oxidation ◽  
P450 2D6

Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts

2002 ◽  
Vol 344 (10) ◽  
pp. 1120-1125 ◽  
Author(s):  
Mario De bruyn ◽  
Dirk E. De Vos ◽  
Pierre A. Jacobs
Keyword(s):  
Hydrogen Transfer ◽  
Allylic Alcohols ◽  
Unsaturated Ketones

Synthesis of the New Chiral Aminodiphosphine Ligands (R)- and (S)-(.alpha.-Methylbenzyl)bis(2-(diphenylphosphino)ethyl)amine and Their Use in the Enantioselective Reduction of .alpha.,.beta.-Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis

1995 ◽  
Vol 14 (3) ◽  
pp. 1489-1502 ◽  
Author(s):  
Claudio Bianchini ◽  
Erica Farnetti ◽  
Lionel Glendenning ◽  
Mauro Graziani ◽  
Giorgio Nardin ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Unsaturated Ketones ◽  
Iridium Catalysis ◽  
Enantioselective Reduction ◽  
Alpha Beta ◽  
Ethyl Amine
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