Regio‐ and Enantioselective Synthesis of Sulfone‐Bearing Quaternary Carbon Stereocenters by Pd‐Catalyzed Allylic Substitution

Ajmal Khan; Heng Zhao; Meina Zhang; Shahid Khan; Depeng Zhao

doi:10.1002/anie.201910378

Regio‐ and Enantioselective Synthesis of Sulfone‐Bearing Quaternary Carbon Stereocenters by Pd‐Catalyzed Allylic Substitution

Angewandte Chemie International Edition ◽

10.1002/anie.201910378 ◽

2019 ◽

Vol 59 (3) ◽

pp. 1340-1345 ◽

Cited By ~ 15

Author(s):

Ajmal Khan ◽

Heng Zhao ◽

Meina Zhang ◽

Shahid Khan ◽

Depeng Zhao

Keyword(s):

Enantioselective Synthesis ◽

Allylic Substitution ◽

Quaternary Carbon

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Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents

Journal of the American Chemical Society ◽

10.1021/ja2010829 ◽

2011 ◽

Vol 133 (13) ◽

pp. 4778-4781 ◽

Cited By ~ 105

Author(s):

Jennifer A. Dabrowski ◽

Fang Gao ◽

Amir H. Hoveyda

Keyword(s):

Enantioselective Synthesis ◽

Allylic Substitution ◽

Quaternary Carbon ◽

Substitution Reactions ◽

Stereogenic Centers

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Regio‐ and Enantioselective Synthesis of Sulfone‐Bearing Quaternary Carbon Stereocenters by Pd‐Catalyzed Allylic Substitution

Angewandte Chemie ◽

10.1002/ange.201910378 ◽

2019 ◽

Vol 132 (3) ◽

pp. 1356-1361 ◽

Cited By ~ 2

Author(s):

Ajmal Khan ◽

Heng Zhao ◽

Meina Zhang ◽

Shahid Khan ◽

Depeng Zhao

Keyword(s):

Enantioselective Synthesis ◽

Allylic Substitution ◽

Quaternary Carbon

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ChemInform Abstract: Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers Through NHC-Cu-Catalyzed Allylic Substitution Reactions with (iBu)2(Alkynyl)aluminum Reagents.

ChemInform ◽

10.1002/chin.201134060 ◽

2011 ◽

Vol 42 (34) ◽

pp. no-no

Author(s):

Jennifer A. Dabrowski ◽

Fang Gao ◽

Amir H. Hoveyda

Keyword(s):

Enantioselective Synthesis ◽

Allylic Substitution ◽

Quaternary Carbon ◽

Substitution Reactions ◽

Stereogenic Centers

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Sequential Asymmetric Catalysis in Michael–Michael–Michael–Aldol Reactions: Merging Organocatalysis with Photoredox Catalysis in a One-Pot Enantioselective Synthesis of Highly Functionalized Decalines Bearing a Quaternary Carbon Stereocenter

Organic Letters ◽

10.1021/ol403113c ◽

2013 ◽

Vol 15 (24) ◽

pp. 6258-6261 ◽

Cited By ~ 33

Author(s):

Bor-Cherng Hong ◽

Cheng-Wei Lin ◽

Wei-Kai Liao ◽

Gene-Hsiang Lee

Keyword(s):

Asymmetric Catalysis ◽

Enantioselective Synthesis ◽

Aldol Reactions ◽

Photoredox Catalysis ◽

Quaternary Carbon ◽

One Pot

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Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Conjugate Additions of Aryl- and Alkylaluminum Reagents to Acyclic Trisubstituted Enones

Angewandte Chemie International Edition ◽

10.1002/anie.201304035 ◽

2013 ◽

Vol 52 (31) ◽

pp. 8156-8159 ◽

Cited By ~ 46

Author(s):

Jennifer A. Dabrowski ◽

Matthew T. Villaume ◽

Amir H. Hoveyda

Keyword(s):

Enantioselective Synthesis ◽

Quaternary Carbon ◽

Conjugate Additions ◽

Stereogenic Centers

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Stereocontrolled Elaboration of Quaternary Carbon Centers through the Asymmetric Michael Reaction Using Chiral Imines: Enantioselective Synthesis of (+)-Aspidospermidine

The Journal of Organic Chemistry ◽

10.1021/jo00088a008 ◽

1994 ◽

Vol 59 (9) ◽

pp. 2292-2303 ◽

Cited By ~ 71

Author(s):

Didier Desmaeele ◽

Jean d'Angelo

Keyword(s):

Michael Reaction ◽

Enantioselective Synthesis ◽

Quaternary Carbon ◽

Carbon Centers ◽

Asymmetric Michael Reaction ◽

Chiral Imines

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Modular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Copper-Catalyzed Allylic Substitutions

Angewandte Chemie International Edition ◽

10.1002/1521-3773(20010417)40:8<1456::aid-anie1456>3.0.co;2-t ◽

2001 ◽

Vol 40 (8) ◽

pp. 1456-1460 ◽

Cited By ~ 121

Author(s):

Courtney A. Luchaco-Cullis ◽

Hirotake Mizutani ◽

Kerry E. Murphy ◽

Amir H. Hoveyda

Keyword(s):

Asymmetric Catalysis ◽

Peptide Ligands ◽

Enantioselective Synthesis ◽

Quaternary Carbon ◽

Allylic Substitutions

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Stereospecific and Stereodivergent Construction of Quaternary Carbon Centers through Switchable Directed/Nondirected Allylic Substitution

Angewandte Chemie International Edition ◽

10.1002/anie.200453991 ◽

2004 ◽

Vol 43 (29) ◽

pp. 3786-3789 ◽

Cited By ~ 55

Author(s):

Bernhard Breit ◽

Peter Demel ◽

Christopher Studte

Keyword(s):

Allylic Substitution ◽

Quaternary Carbon ◽

Carbon Centers

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Cooperative Catalysis in Multicomponent Reactions: Highly Enantioselective Synthesis of γ-Hydroxyketones with a Quaternary Carbon Stereocenter

Angewandte Chemie ◽

10.1002/ange.200904905 ◽

2010 ◽

Vol 122 (12) ◽

pp. 2236-2238 ◽

Cited By ~ 32

Author(s):

Xiao-Yu Guan ◽

Li-Ping Yang ◽

Wenhao Hu

Keyword(s):

Multicomponent Reactions ◽

Enantioselective Synthesis ◽

Quaternary Carbon ◽

Cooperative Catalysis

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ChemInform Abstract: Enantioselective Synthesis of Quaternary Carbon Stereocenters: Addition of 3-Substituted Oxindoles to Vinyl Sulfone Catalyzed by Pentanidiums.

ChemInform ◽

10.1002/chin.201548130 ◽

2015 ◽

Vol 46 (48) ◽

pp. no-no

Author(s):

Lili Zong ◽

Shubo Du ◽

Kek Foo Chin ◽

Chao Wang ◽

Choon-Hong Tan

Keyword(s):

Enantioselective Synthesis ◽

Vinyl Sulfone ◽

Quaternary Carbon

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