scholarly journals Tuning the H‐atom transfer reactivity of iron(IV)‐oxo complexes as probed by infrared photodissociation spectroscopy

2021 ◽  
Author(s):  
Guilherme L. Tripodi ◽  
Magda Dekker ◽  
Jana Roithová ◽  
Lawrence Que
Keyword(s):  
Atom Transfer ◽  
Oxo Complexes

Nonheme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and Their Hydrogen-Atom and Oxygen-Atom Transfer Reactions

2015 ◽  
Vol 54 (15) ◽  
pp. 7152-7164 ◽  
Author(s):  
Mainak Mitra ◽  
Hassan Nimir ◽  
Serhiy Demeshko ◽  
Satish S. Bhat ◽  
Sergey O. Malinkin ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Oxygen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxo Complexes ◽  
Pentadentate Ligands ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

scholarly journals Hydrogen-atom and oxygen-atom transfer reactivities of iron(iv)-oxo complexes of quinoline-substituted pentadentate ligands

2022 ◽  
Author(s):  
Sandip Munshi ◽  
Arup Sinha ◽  
Solomon Yiga ◽  
Sridhar Banerjee ◽  
Reena Singh ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Oxygen Atom ◽  
Electronic Properties ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxo Complexes ◽  
Pentadentate Ligands

The reactivities of Fe(iv) oxido complexes of two pentadentate ligands are related to steric and electronic properties of the ligands.

Importance of the Reactant-State Potentials of Chromium(V)–Oxo Complexes to Determine the Reactivity in Hydrogen-Atom Transfer Reactions

2018 ◽  
Vol 57 (21) ◽  
pp. 13929-13936 ◽  
Author(s):  
Hiroaki Kotani ◽  
Suzue Kaida ◽  
Tomoya Ishizuka ◽  
Kaoru Mieda ◽  
Miyuki Sakaguchi ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxo Complexes ◽  
Atom Transfer Reactions

scholarly journals Tuning the H‐atom transfer reactivity of iron(IV)‐oxo complexes as probed by infrared photodissociation spectroscopy

2021 ◽  
Author(s):  
Guilherme L. Tripodi ◽  
Magda Dekker ◽  
Jana Roithová ◽  
Lawrence Que
Keyword(s):  
Atom Transfer ◽  
Oxo Complexes

scholarly journals Oxygen-Atom Transfer Reactivity of Axially Ligated Mn(V)–Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways

2014 ◽  
Vol 136 (39) ◽  
pp. 13845-13852 ◽  
Author(s):  
Heather M. Neu ◽  
Tzuhsiung Yang ◽  
Regina A. Baglia ◽  
Timothy H. Yosca ◽  
Michael T. Green ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxo Complexes

Direct oxygen atom transfer versus electron transfer mechanisms in the phosphine oxidation by nonheme Mn(iv)-oxo complexes

2017 ◽  
Vol 53 (67) ◽  
pp. 9352-9355 ◽  
Author(s):  
Yong-Min Lee ◽  
Mi Yoo ◽  
Heejung Yoon ◽  
Xiao-Xi Li ◽  
Wonwoo Nam ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Oxygen Atom ◽  
Phenyl Group ◽  
Steric Effects ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxo Complexes ◽  
Transfer Mechanisms

Direct oxygen atom transfer from Mn(iv)-oxo to Ph3P occurs, exhibiting significant steric effects of the ortho-substitution of the phenyl group, whereas in the presence of HOTf, the mechanism is switched to electron transfer from Ph3P to Mn(iv)-oxo, exhibiting no steric effects.

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