Triruthenium carbonyl complexes containing bidentate pyridine–alkoxide ligands for highly efficient oxidation of primary and secondary alcohols

2019 ◽  
Vol 34 (1) ◽  
Author(s):  
Xiaohui Yue ◽  
Xinlong Yan ◽  
Shuaicong Huo ◽  
Qing Dong ◽  
Junhua Zhang ◽  
...  
Keyword(s):  
Secondary Alcohols ◽  
Carbonyl Complexes ◽  
Highly Efficient ◽  
Alkoxide Ligands

Ruthenium carbonyl complexes supported by pyridine-alkoxide ligands: synthesis, structure and catalytic oxidation of secondary alcohols

2019 ◽  
Vol 43 (35) ◽  
pp. 13947-13953 ◽  
Author(s):  
Siqi Zong ◽  
Kang Liu ◽  
Xiaohui Yue ◽  
Zhiqiang Hao ◽  
Zhihong Ma ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Secondary Alcohols ◽  
Carbonyl Complexes ◽  
Ruthenium Carbonyl ◽  
Alkoxide Ligands

Five novel trinuclear ruthenium carbonyl complexes were synthesized and their application in oxidation of secondary alcohols was also researched.

Ruthenium carbonyl complexes with pyridine-alkoxide ligands: synthesis, characterization and catalytic application in dehydrogenative oxidation of alcohols

2018 ◽  
Vol 42 (18) ◽  
pp. 15472-15478 ◽  
Author(s):  
Zhiqiang Hao ◽  
Xinlong Yan ◽  
Kang Liu ◽  
Xiaohui Yue ◽  
Zhangang Han ◽  
...  
Keyword(s):  
Secondary Alcohols ◽  
Carbonyl Complexes ◽  
Mild Conditions ◽  
Catalytic Application ◽  
Ruthenium Carbonyl ◽  
Oxidation Of Alcohols ◽  
Alkoxide Ligands

Dehydrogenative oxidation of secondary alcohols catalyzed by several new trinuclear ruthenium carbonyl complexes under mild conditions was proposed.

A Highly Efficient Conversion of Primary or Secondary Alcohols into Fluorides with n-Perfluorobutanesulfonyl Fluoride-Tetrabutylammonium Triphenyldifluorosilicate

Synlett ◽  
2009 ◽  
Vol 2009 (05) ◽  
pp. 779-782 ◽  
Author(s):  
Xueqing Zhao ◽  
Xiaowen Xue ◽  
Weiping Zhuang ◽  
Dongsheng Fang ◽  
Jingming Zhou
Keyword(s):  
Secondary Alcohols ◽  
Efficient Conversion ◽  
Highly Efficient

Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2

2014 ◽  
Vol 17 (1) ◽  
pp. 54-57 ◽  
Author(s):  
Duyi Shen ◽  
Chengxia Miao ◽  
Daqian Xu ◽  
Chungu Xia ◽  
Wei Sun
Keyword(s):  
Manganese Complexes ◽  
Secondary Alcohols ◽  
Highly Efficient

scholarly journals Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water

Molecules ◽  
2018 ◽  
Vol 23 (8) ◽  
pp. 1883 ◽  
Author(s):  
Shi-juan Liu ◽  
Miao Zhang ◽  
Rong Lu ◽  
Xiu-ying Li ◽  
Guang-bo Che
Keyword(s):  
Catalytic System ◽  
Functional Group ◽  
Secondary Alcohols ◽  
Benzylic Alcohols ◽  
Highly Efficient ◽  
Aryl Ketones ◽  
Sodium Copper Chlorophyllin

We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, secondary alcohols and even diarylmethanes were smoothly oxidized to the desired aryl ketones with excellent yields.

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