Grafting of maleic anhydride onto styrene–butadiene–styrene triblock copolymer using supercritical CO2 as a swelling agent

2006 ◽  
Vol 102 (5) ◽  
pp. 4425-4429 ◽  
Author(s):  
Chunsheng Li ◽  
Shuxiang Zhang ◽  
Anna Zheng ◽  
Xiangzheng Kong ◽  
Bing Geng
Keyword(s):  
Maleic Anhydride ◽  
Supercritical Co2 ◽  
Triblock Copolymer ◽  
Swelling Agent ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Functionalization of styrene-butadiene-styrene (SBS) triblock copolymer with maleic anhydride

2001 ◽  
Vol 46 (6) ◽  
pp. 491-498 ◽  
Author(s):  
Carlota H. F. Maurano ◽  
Liliane L. Portal ◽  
Ricardo Baumhardt Neto ◽  
Raquel S. Mauler
Keyword(s):  
Maleic Anhydride ◽  
Triblock Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Compatibility and Storage Stability of Asphalt Binder Modified by Styrene-Butadiene-Styrene (SBS) Graft Copolymer

2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  
Keyword(s):  
Triblock Copolymer ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Solubility Parameters ◽  
Suitable Alternative ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.

Rheology of Styrene‐Butadiene‐Styrene Triblock Copolymer in n‐Tetradecane Systems

1984 ◽  
Vol 28 (4) ◽  
pp. 393-409 ◽  
Author(s):  
Hiroshi Watanabe ◽  
Souichiro Kuwahara ◽  
Tadao Kotaka
Keyword(s):  
Triblock Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene
Sign in / Sign up

Export Citation Format

Share Document