Quaternized poly(phenylene oxide) anion exchange membrane for alkaline direct methanol fuel cells in KOH-free media

2016 ◽  
Vol 133 (29) ◽  
Author(s):  
K. Hari Gopi ◽  
Santoshkumar D. Bhat ◽  
Akhila Kumar Sahu ◽  
P. Sridhar
RSC Advances ◽  
2015 ◽  
Vol 5 (78) ◽  
pp. 63215-63225 ◽  
Author(s):  
Xiaohui He ◽  
Jingyin Liu ◽  
Hongyu Zhu ◽  
Yan Zheng ◽  
Defu Chen

Novel quaternary ammonium functional addition-type norbornene copolymers, and their anion exchange membranes with effective hydrophilic–hydrophobic separation and well performance suitable for direct methanol fuel cells application are achieved.


Author(s):  
Hang Guo ◽  
Chong Fang Ma ◽  
Mao Hai Wang ◽  
Jian Yu ◽  
Xuan Liu ◽  
...  

Fuel cells are related to a number of scientific and engineering disciplines, which include electrochemistry, catalysis, membrane science and engineering, heat and mass transfer, thermodynamics and so on. Several thermophysical phenomena such as heat transfer, multicomponent transport and two phase flow play significant roles in hydrogen proton exchange membrane fuel cells and direct methanol fuel cells based on solid polymer electrolyte membrane. Some coupled thermophysical issues are bottleneck in process of scale-up of direct methanol fuel cells and hydrogen proton exchange membrane fuel cells. In present paper, experimental results of visualization of condensed water in fuel cell cathode microchannels are presented. The equivalent diameter of the rectangular channel is 0.8mm. Water droplets from the order of 0.08mm to 0.8mm were observed from several different locations in the channels. Several important problems, such as generation and change characteristics of water droplet and gas bubble, two phase flow under chemical reaction conditions, mass transfer enhancement of oxygen in the cathode porous media layer, heat transfer enhancement and high efficiency cooling system of proton exchange membrane fuel cells stack, etc., are discussed.


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