A Combined Flash Photolysis/Shock-Tube Study of the Absolute Rate Constants for Reactions of the Hydroxyl Radical with CH4and CF3H around 1300 K

1978 ◽  
Vol 82 (4) ◽  
pp. 409-414 ◽  
Author(s):  
J. Ernst ◽  
H. Gg. Wagner ◽  
R. Zellner
Keyword(s):  
Shock Tube ◽  
Hydroxyl Radical ◽  
Rate Constants ◽  
Flash Photolysis ◽  
Absolute Rate ◽  
The Absolute ◽  
Tube Study

Reactions of the hydroxyl radical. Part 2.—Determination of absolute rate constants

1965 ◽  
Vol 61 (0) ◽  
pp. 1417-1424 ◽  
Author(s):  
G. E. Adams ◽  
J. W. Boag ◽  
B. D. Michael
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constants ◽  
Absolute Rate

Determination of the Absolute Rate Constants in Free-Radical Polymerization of Zwitterionic Sulfobetaine Monomers

1993 ◽  
Vol 30 (1) ◽  
pp. 51-58 ◽  
Author(s):  
Der-jang Liaw ◽  
Jen-rong lin ◽  
Kwang-chih Chung
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Rate Constants ◽  
Free Radical Polymerization ◽  
Absolute Rate ◽  
The Absolute

Determination of the Absolute Rate Constants of Propagation for Ion Pairs in the Carbocationic Polymerization ofp-Chlorostyrene

2004 ◽  
Vol 37 (24) ◽  
pp. 9290-9294 ◽  
Author(s):  
Priyadarsi De ◽  
Rudolf Faust
Keyword(s):  
Rate Constants ◽  
Ion Pairs ◽  
Absolute Rate ◽  
Carbocationic Polymerization ◽  
The Absolute

scholarly journals Determination of the Absolute Rate Constants for Free-Radical Polymerization

1981 ◽  
Vol 13 (5) ◽  
pp. 453-457 ◽  
Author(s):  
Kuo Jen-Feng ◽  
Chen Chuh-Yung
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Rate Constants ◽  
Free Radical Polymerization ◽  
Absolute Rate ◽  
The Absolute

Absolute Rate Constants and Yields of Transients from Hydroxyl Radical and H Atom Attack on Glycine and Methyl-Substituted Glycine Anions

2001 ◽  
Vol 105 (38) ◽  
pp. 8681-8690 ◽  
Author(s):  
Igor Štefanić ◽  
Marija Bonifačić ◽  
Klaus-Dieter Asmus ◽  
David A. Armstrong
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constants ◽  
Absolute Rate

The reactions of O(3P) with 2-propanone, 2-butanone, and 3-pentanone

1986 ◽  
Vol 64 (7) ◽  
pp. 1408-1414 ◽  
Author(s):  
John M. Roscoe
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Substrate Concentration ◽  
Activation Energies ◽  
Absolute Rate ◽  
The Absolute

The reactions of O(3P) with 2-propanone, 2-butanone, and 3-pentanone have been studied kinetically as a function of temperature and substrate concentration. The absolute rate constants for these reactions in the gas phase, in the units M−1 s−1, obey the following relations.[Formula: see text]The activation energies for these reactions are comparable to those for the reactions of O(3P) with alcohols, but the preexponential factors for the reactions of O(3P) with these ketones are significantly smaller than those for the analogous reactions with alcohols. The available data indicate that the reactivity of O(3P) toward ketones shows a variation with polar effects of substituents which is similar to that found for the reactions of OH with ketones.

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