The effect of counter-ion substitution on the transport properties of polyelectrolyte solutions

Biopolymers ◽  
1979 ◽  
Vol 18 (1) ◽  
pp. 187-201 ◽  
Author(s):  
H. Magdelénat ◽  
P. Turr ◽  
P. Tivant ◽  
M. Chemla ◽  
R. Menez ◽  
...  
2015 ◽  
Vol 229 (7-8) ◽  
Author(s):  
Jérôme Delacotte ◽  
Dominique Langevin

AbstractThe role of condensed counterions in transport properties, such as electrical conductivity and viscosity, has been investigated with solutions of a flexible polyelectrolyte. Comparisons with existing theories are proposed. Viscosity is strongly affected by confinement in thin films, depending whether polyelectrolyte chains are adsorbed or not at the film surfaces. The role of counterion mobility is however difficult to assess because the measurements are not accurate enough. It is proposed that this role could be tested by electrical conductivity measurements.


2014 ◽  
Vol 131 (11) ◽  
pp. n/a-n/a ◽  
Author(s):  
David Suleiman ◽  
Agnes M. Padovani ◽  
Arnaldo A. Negrón ◽  
James M. Sloan ◽  
Eugene Napadensky ◽  
...  

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