Transition Metal Complexes with Sulfur Ligands, Part 119. Synthesis of Water Soluble Fe and Ru Complexes with Novel Multidentate Thioether Thiolate Ligands Containing Carboxylate Substituents

1996 ◽  
Vol 129 (5) ◽  
pp. 509-519 ◽  
Author(s):  
Dieter Sellmann ◽  
Thomas Becker ◽  
Falk Knoch
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Water Soluble ◽  
Thiolate Ligands ◽  
Ru Complexes

Water-soluble aminomethyl(ferrocenylmethyl)phosphines and their trinuclear transition metal complexes

Polyhedron ◽  
2002 ◽  
Vol 21 (22) ◽  
pp. 2251-2256 ◽  
Author(s):  
Andrey A Karasik ◽  
Roman N Naumov ◽  
René Sommer ◽  
Oleg G Sinyashin ◽  
Evamarie Hey-Hawkins
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Water Soluble

scholarly journals The photochemistry of transition metal complexes using density functional theory

2013 ◽  
Vol 371 (1995) ◽  
pp. 20120134 ◽  
Author(s):  
Claudio Garino ◽  
Luca Salassa
Keyword(s):  
Density Functional Theory ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Density Functional ◽  
Organometallic Complexes ◽  
Functional Theory ◽  
Td Dft ◽  
Ru Complexes ◽  
Active Transition

The use of density functional theory (DFT) and time-dependent DFT (TD-DFT) to study the photochemistry of metal complexes is becoming increasingly important among chemists. Computational methods provide unique information on the electronic nature of excited states and their atomic structure, integrating spectroscopy observations on transient species and excited-state dynamics. In this contribution, we present an overview on photochemically active transition metal complexes investigated by DFT. In particular, we discuss a representative range of systems studied up to now, which include CO- and NO-releasing inorganic and organometallic complexes, haem and haem-like complexes dissociating small diatomic molecules, photoactive anti-cancer Pt and Ru complexes, Ru polypyridyls and diphosphino Pt derivatives.

scholarly journals Supramolecular control of transition metal complexes in water by a hydrophobic cavity: a bio-inspired strategy

2015 ◽  
Vol 13 (10) ◽  
pp. 2849-2865 ◽  
Author(s):  
Olivia Bistri ◽  
Olivia Reinaud
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Water Soluble ◽  
Hydrophobic Cavity ◽  
Supramolecular Control

Different strategies for obtaining water-soluble cavity-appended metal complexes are described, and their resulting interlocked assets are discussed in relationship with the very specific properties of water as a solvent.

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