Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions

ChemCatChem ◽  
2015 ◽  
Vol 7 (6) ◽  
pp. 1023-1028 ◽  
Author(s):  
Jong-Hoo Choi ◽  
Martin H. G. Prechtl
Keyword(s):  
Mild Conditions ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex

2015 ◽  
Vol 137 (28) ◽  
pp. 8888-8891 ◽  
Author(s):  
Arup Mukherjee ◽  
Dipankar Srimani ◽  
Subrata Chakraborty ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Selective Hydrogenation ◽  
Primary Amines ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

A New Supported Rhodium Catalyst for Selective Hydrogenation of Nitriles to Primary Amines

2007 ◽  
Vol 72 (4) ◽  
pp. 468-474 ◽  
Author(s):  
Peter T. Witte
Keyword(s):  
Selective Hydrogenation ◽  
High Selectivity ◽  
Rhodium Catalyst ◽  
Primary Amines ◽  
Mild Conditions ◽  
Pharmaceutical Applications ◽  
Strong Acids ◽  
Hydrogenation Of Nitriles ◽  
Supported Rhodium Catalyst

Nitriles are converted to primary amines with high selectivity using a newly developed alumina-supported rhodium catalyst. The high selectivity is obtained without any additives, which are often used to prevent the formation of higher amines. The catalyst is active under mild conditions in various solvents, which makes it specifically suitable for use in pharmaceutical applications or for other substrates that can react with additives like strong acids or bases.

scholarly journals Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium–NHC–pincer complex

2015 ◽  
Vol 51 (10) ◽  
pp. 1897-1900 ◽  
Author(s):  
Eva Jürgens ◽  
Barbara Wucher ◽  
Frank Rominger ◽  
Karl W. Törnroos ◽  
Doris Kunz
Keyword(s):  
High Yield ◽  
Mild Conditions ◽  
Pincer Complex ◽  
Very High

The highly nucleophilic complex 1 isomerises terminal epoxides exclusively to the respective methylketones in very high yield under mild conditions.

A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions

2019 ◽  
Vol 21 (9) ◽  
pp. 3142-3147 ◽  
Author(s):  
Leonard Homberg ◽  
Alexander Roller ◽  
Kai C. Hultzsch
Keyword(s):  
Mild Conditions ◽  
Highly Active ◽  
Pincer Complex

ChemInform Abstract: Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex.

ChemInform ◽  
2015 ◽  
Vol 46 (52) ◽  
pp. no-no
Author(s):  
Arup Mukherjee ◽  
Dipankar Srimani ◽  
Subrata Chakraborty ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Selective Hydrogenation ◽  
Primary Amines ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex

ACS Catalysis ◽  
2017 ◽  
Vol 7 (6) ◽  
pp. 3968-3972 ◽  
Author(s):  
Subrata Chakraborty ◽  
David Milstein
Keyword(s):  
Selective Hydrogenation ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

scholarly journals Selective Hydrogenation of Nitriles to Secondary Imines over Rh-PVP Catalyst under Mild Conditions

2018 ◽  
Vol 47 (7) ◽  
pp. 938-940 ◽  
Author(s):  
Yoshihide Nishida ◽  
Chandan Chaudhari ◽  
Hirotaka Imatome ◽  
Katsutoshi Sato ◽  
Katsutoshi Nagaoka
Keyword(s):  
Selective Hydrogenation ◽  
Mild Conditions ◽  
Hydrogenation Of Nitriles
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