ChemInform Abstract: Stereoselective Pincer-Complex Catalyzed C-H Functionalization of Benzyl Nitriles under Mild Conditions. An Efficient Route to β-Aminonitriles.

ChemInform ◽  
2009 ◽  
Vol 40 (15) ◽  
Author(s):  
Juhanes Aydin ◽  
Cathrin S. Conrad ◽  
Kalman J. Szabo
Keyword(s):  
Mild Conditions ◽  
Pincer Complex ◽  
Efficient Route

Insertion of sulfur dioxide via a radical process: an efficient route to sulfonyl compounds

2018 ◽  
Vol 5 (4) ◽  
pp. 691-705 ◽  
Author(s):  
Guanyinsheng Qiu ◽  
Kaida Zhou ◽  
Liang Gao ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Radical Process ◽  
Mild Conditions ◽  
Recent Advances ◽  
Efficient Route

This review is focused on the recent advances in the chemistry of sulfur dioxide fixation through a radical process. Diverse sulfonyl compounds can be obtained efficiently under mild conditions.

scholarly journals Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium–NHC–pincer complex

2015 ◽  
Vol 51 (10) ◽  
pp. 1897-1900 ◽  
Author(s):  
Eva Jürgens ◽  
Barbara Wucher ◽  
Frank Rominger ◽  
Karl W. Törnroos ◽  
Doris Kunz
Keyword(s):  
High Yield ◽  
Mild Conditions ◽  
Pincer Complex ◽  
Very High

The highly nucleophilic complex 1 isomerises terminal epoxides exclusively to the respective methylketones in very high yield under mild conditions.

A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions

2019 ◽  
Vol 21 (9) ◽  
pp. 3142-3147 ◽  
Author(s):  
Leonard Homberg ◽  
Alexander Roller ◽  
Kai C. Hultzsch
Keyword(s):  
Mild Conditions ◽  
Highly Active ◽  
Pincer Complex

Synthesis of trisubstituted hydroxylamines by a visible light-promoted multicomponent reaction

2021 ◽  
Author(s):  
Bao-Gui Cai ◽  
Qian Li ◽  
Qiong Zhang ◽  
Lei Li ◽  
Jun Xuan
Keyword(s):  
Visible Light ◽  
Multicomponent Reaction ◽  
Keto Ester ◽  
Mild Conditions ◽  
Efficient Route

A green and efficient route for the synthesis of trisubstituted hydroxylamines from β-keto ester, 2-nitrosopyridine and aryldiazoacetates has been reported. This multicomponent reaction occurred under mild conditions without catalysts or additives.

Efficient route for oxazolidinone synthesis using heterogeneous biopolymer catalysts from unactivated alkyl aziridine and CO2 under mild conditions

2012 ◽  
Vol 447-448 ◽  
pp. 107-114 ◽  
Author(s):  
Amal Cherian Kathalikkattil ◽  
Jose Tharun ◽  
Roshith Roshan ◽  
Han-Geul Soek ◽  
Dae-Won Park
Keyword(s):  
Mild Conditions ◽  
Efficient Route

scholarly journals A New Efficient Route to 2-Alkylsemicarbazides

Proceedings ◽  
2019 ◽  
Vol 41 (1) ◽  
pp. 46
Author(s):  
Anastasia A. Fesenko ◽  
Ludmila A. Trafimova ◽  
Maxim O. Zimin ◽  
Alexander S. Kuvakin ◽  
Anatoly D. Shutalev
Keyword(s):  
Sodium Hydride ◽  
Mild Conditions ◽  
Semicarbazide Hydrochloride ◽  
Efficient Route

Synthesis of hardly available 2-alkylsemicarbazides and their hydrochlorides from semicarbazide hydrochloride has been developed. This general and efficient protocol is based on preparation of acetone semicarbazone, its N2-alkylation in the presence of sodium hydride, and hydrolysis under mild conditions.

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