Moderately concentrated acetonitrile‐containing electrolytes with high ionic conductivity for durability‐oriented lithium‐ion batteries

2021 ◽  
Author(s):  
Naoki Matsuoka ◽  
Hirokazu Kamine ◽  
Yutaka Natsume ◽  
Akira Yoshino
2016 ◽  
Vol 34 (3) ◽  
pp. 605-616 ◽  
Author(s):  
K. Vijaya Babu ◽  
V. Veeraiah

AbstractThe most attractive property of Li0.5La0.5TiO3 (LLTO) electrolytes is their high ionic conductivity. Studies have shown that LLTO is capable of existing in a state with an ionic conductivity of 10-3 S/cm, which is comparable to liquid electrolytes. In addition to the high ionic conductivity of the material, LLTO is electrochemically stable and able to withstand hundreds of cycles. So, the studies of the solid electrolyte material are very important for the development of lithium-ion batteries. In the present paper, Li0.5La0.5Ti1-xZrxO3 (x = 0.05 and 0.1) have been prepared by a solid-state reaction method at 1300 °C for 6 hours to improve electrolyte materials for lithium-ion batteries. The phase identified by X-ray diffractometry and crystal structure corresponds to pm3m (2 2 1) space group (Z = 1). The frequency and temperature dependence of impedance, dielectric permittivity, dielectric loss and electric modulus of the Li0.5La0.5Ti1-xZrxO3 (x = 0.05 and 0.1) have been investigated. The dielectric and impedance properties have been studied over a range of frequency (42 Hz to 5 MHz) and temperatures (30 °C to 100 °C). The frequency dependent plot of modulus shows that the conductivity relaxation is of non-Debye type.


Nanoscale ◽  
2021 ◽  
Author(s):  
Mengmeng Gao ◽  
Xiaolei Wu ◽  
Shuhong Yi ◽  
Shuwei Sun ◽  
Caiyan Yu ◽  
...  

Upgrading liquid electrolytes with all-solid-state electrolytes (ASEs) or quasi-solid-state electrolytes (QSEs) for solid-state batteries (SBs) have emerged not only to address the intrinsic disadvantages of traditional liquid lithium ion batteries,...


2020 ◽  
Vol 8 (2) ◽  
pp. 706-713 ◽  
Author(s):  
Jiaying Bi ◽  
Daobin Mu ◽  
Borong Wu ◽  
Jiale Fu ◽  
Hao Yang ◽  
...  

An LLTO/PAN/SNE hybrid solid electrolyte membrane with high ionic conductivity and excellent compatibility with both LiFePO4 cathode and metallic lithium anode.


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