From Allylic Alcohols to Aldols through a New Nickel-Mediated Tandem Reaction: Synthetic and Mechanistic Studies

2006 ◽  
Vol 12 (12) ◽  
pp. 3261-3274 ◽  
Author(s):  
David Cuperly ◽  
Julien Petrignet ◽  
Christophe Crévisy ◽  
René Grée
Keyword(s):  
Tandem Reaction ◽  
Allylic Alcohols ◽  
Mechanistic Studies

Phosphine-Catalyzed Synthesis of 3-Allyl-4-pyrones by the Tandem Reaction of Diynones and Allylic Alcohols

2021 ◽  
Author(s):  
Ya-Fang Ye ◽  
Wan-Wan Yang ◽  
Jing-Wen Zhang ◽  
Ji-Ya Fu ◽  
Jun-Yan Zhu ◽  
...  
Keyword(s):  
Tandem Reaction ◽  
Allylic Alcohols

RhodiumIII-Catalyzed Successive Csp2‒H and Csp2‒Csp2 Bond Activation of Aryl Oximes: Synthetic and Mechanistic Studies

2022 ◽  
Author(s):  
Guo-Jun Deng ◽  
Cheng Li ◽  
Fuhong Xiao ◽  
Huawen Huang ◽  
Bin Zhao
Keyword(s):  
Bond Activation ◽  
Raw Materials ◽  
Tandem Reaction ◽  
Mechanistic Studies ◽  
Practical Strategy

Merging selective C–H cleavage with C–C cleavage in a tandem reaction has been a practical strategy that permits skeletal diversification from simple raw materials. Herein, we describe a rhodiumIII-catalyzed redox-neutral...

Catalytic enantioselective synthesis of indolizino[8,7-b]indole alkaloid derivatives based on the tandem reaction of tertiary enamides

2021 ◽  
Author(s):  
Xin-Ming Xu ◽  
Ming Xie ◽  
Jiazhu Li ◽  
Mei-Xiang Wang
Keyword(s):  
Indole Alkaloid ◽  
Enantioselective Synthesis ◽  
High Yield ◽  
Tandem Reaction ◽  
Indole Derivatives

An exquisite Pybox/Cu(OTf)2-catalyzed asymmetric tandem reaction of tertiary enamides was developed, which enabled the expeditious synthesis of indolizino[8,7-b]indole derivatives in high yield, excellent enantioselectivity and diastereoselectivity.

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