Metal Amides as the Simplest Acid/Base Catalysts for Stereoselective Carbon-Carbon Bond-Forming Reactions

2013 ◽  
Vol 19 (29) ◽  
pp. 9420-9427 ◽  
Author(s):  
Yasuhiro Yamashita ◽  
Shū Kobayashi
Keyword(s):  
Acid Base ◽  
Carbon Bond ◽  
Bond Forming ◽  
Base Catalysts ◽  
Metal Amides ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Development of Chiral Potassium Strong Brønsted Base Catalysts for Enantioselective Carbon–Carbon Bond-Forming Reactions

2022 ◽  
Author(s):  
Yasuhiro Yamashita
Keyword(s):  
Enantioselective Catalysis ◽  
Alkaline Metal ◽  
Strong Base ◽  
Carbon Bond ◽  
Bond Forming ◽  
Base Catalysts ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Brønsted Base

Chiral alkaline metal Brønsted bases are traditional and reliable promoters in enantioselective catalysis. Here, new chiral potassium strong base catalysts were developed for enantioselective carbon–carbon bond-forming reactions of weakly acidic...

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