From Chiral Base Catalysts to Redox-Active Catalysts: Chasing the Identity of Metal Catalysts in Carbon-Carbon Bond-Forming Reactions

2013 ◽  
Vol 71 (5) ◽  
pp. 433-442 ◽  
Author(s):  
Motomu Kanai ◽  
Shigeki Matsunaga ◽  
Kounosuke Oisaki ◽  
Yohei Shimizu
Keyword(s):  
Metal Catalysts ◽  
Carbon Bond ◽  
Bond Forming ◽  
Base Catalysts ◽  
Carbon Carbon Bond ◽  
Redox Active ◽  
Bond Forming Reactions

Bio-inspired asymmetric aldehyde arylations catalyzed by rhodium-cyclodextrin self-inclusion complexes

2021 ◽  
Author(s):  
Susumu Tsuda ◽  
Kaoru Asahi ◽  
Ryota Takahashi ◽  
Hiroki Yamauchi ◽  
Ryoji Ueda ◽  
...  
Keyword(s):  
Transition Metal ◽  
Inclusion Complexes ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Transition-metal catalysts are powerful tools for carbon–carbon bond-forming reactions that are difficult to achieve using native enzymes. Enzymes that exhibit inherent selectivities and reactivities through host-guest interactions have inspired widespread...

Development of Chiral Potassium Strong Brønsted Base Catalysts for Enantioselective Carbon–Carbon Bond-Forming Reactions

2022 ◽  
Author(s):  
Yasuhiro Yamashita
Keyword(s):  
Enantioselective Catalysis ◽  
Alkaline Metal ◽  
Strong Base ◽  
Carbon Bond ◽  
Bond Forming ◽  
Base Catalysts ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Brønsted Base

Chiral alkaline metal Brønsted bases are traditional and reliable promoters in enantioselective catalysis. Here, new chiral potassium strong base catalysts were developed for enantioselective carbon–carbon bond-forming reactions of weakly acidic...

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