A Unified and Practical Method for Carbon–Heteroatom Cross‐Coupling using Nickel/Photo Dual Catalysis

2020 ◽  
Vol 26 (23) ◽  
pp. 5168-5173 ◽  
Author(s):  
Randolph A. Escobar ◽  
Jeffrey W. Johannes
Author(s):  
Hannah E. Burdge ◽  
Takuya Oguma ◽  
Takahiro Kawajiri ◽  
Ryan Shenvi

<div><div><div><p>The first synthesis of GB22 was accomplished by a con- cise, modular route. Two building blocks converged in a novel sp3-sp2 attached-ring coupling that used Ir/Ni dual-catalysis to reverse the regioselectivity of siloxycy- clopropane arylation. This cross-coupling proved general to access β-substituted tetralones via ring-expansion of indanone-derived siloxycyclopropanes. The congested, bridging rings of the GB alkaloids were completed using an aluminum-HFIP complex that effected intramolecular cyclization of an acid-labile substrate.</p></div></div></div>


2019 ◽  
Author(s):  
Hannah E. Burdge ◽  
Takuya Oguma ◽  
Takahiro Kawajiri ◽  
Ryan Shenvi

<div><div><div><p>The first synthesis of GB22 was accomplished by a con- cise, modular route. Two building blocks converged in a novel sp3-sp2 attached-ring coupling that used Ir/Ni dual-catalysis to reverse the regioselectivity of siloxycy- clopropane arylation. This cross-coupling proved general to access β-substituted tetralones via ring-expansion of indanone-derived siloxycyclopropanes. The congested, bridging rings of the GB alkaloids were completed using an aluminum-HFIP complex that effected intramolecular cyclization of an acid-labile substrate.</p></div></div></div>


2019 ◽  
Vol 10 (19) ◽  
pp. 5073-5078 ◽  
Author(s):  
Hyelee Lee ◽  
Nicolas C. Boyer ◽  
Qiaolin Deng ◽  
Hai-Young Kim ◽  
Tomi K. Sawyer ◽  
...  

Ni/photoredox (4DPAIPN) dual catalysis enabled challenging peptide C(sp2)–O coupling reactions.


RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 1012-1017 ◽  
Author(s):  
Maddali L. N. Rao ◽  
Ritesh J. Dhanorkar

The threefold cross-coupling reactivity of sterically highly demanding bulky triarylbismuths was addressed with task specific Pd–Cu dual catalytic conditions.


2015 ◽  
Vol 17 (13) ◽  
pp. 3294-3297 ◽  
Author(s):  
Idris Karakaya ◽  
David N. Primer ◽  
Gary A. Molander

2016 ◽  
Vol 3 (4) ◽  
pp. 462-465 ◽  
Author(s):  
Christophe Lévêque ◽  
Ludwig Chenneberg ◽  
Vincent Corcé ◽  
Jean-Philippe Goddard ◽  
Cyril Ollivier ◽  
...  

Primary alkyl bis-catecholato silicates have been successfully engaged with aryl and heteroaryl bromide substrates in photoredox/nickel dual catalysis to provide cross coupling products.


Aviation ◽  
2020 ◽  
Vol 24 (4) ◽  
pp. 137-148
Author(s):  
Mostafa Honari-Torshizi ◽  
Hossein Rahmani ◽  
Hossein Moeinkhah ◽  
Mohammad Reza Gharib ◽  
Javad Jahanpour

Control of a Twin Rotor Multi-input Multi-output System (TRMS) is not a simple work. Because it has complex nonlinear dynamics, cross-coupling, uncertainties, and instability. This paper provides a practical method for control of a TRMS, named Quantitative Feedback Theory (QFT) as one of the robust approaches. Firstly, the TRMS set and modeling procedure are introduced. Secondly, the nonlinear and linear equations of electrical and mechanical parts in both vertical and horizontal planes are presented. Next, using the QFT method, a controller is designed for motion in each plane. Finally, the robustness of the control strategy is illustrated by simulations of vertical and horizontal motions, including controller and pre-filter in the presence of uncertainties. The results demonstrate that the proposed robust controller can guarantee the system stabilization, as well as pitch and yaw tracking of TRMS.


2019 ◽  
Vol 59 (1) ◽  
pp. 457-464 ◽  
Author(s):  
Long Huang ◽  
Chen Zhu ◽  
Liang Yi ◽  
Huifeng Yue ◽  
Rajesh Kancherla ◽  
...  

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