Gold‐Catalyzed Oxidative Aminocyclizations of Propargyl Alcohols and Propargyl Amines to Form Two Distinct Azacyclic Products: Carbene Formation versus a 3,3‐Sigmatropic Shift of an Initial Intermediate

A photoinduced sulfonylvinylation of unactivated C(sp3)-H bond through a three-component reaction of propargyl alcohols, potassium metabisulfite and cycloketone oxime esters is developed. This approach enables rapid access to cyanoalkylated vinyl...

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Rhodium-catalyzed oxidative coupling of benzoic acids with propargyl alcohols: An efficient access to isocoumarins

Tetrahedron Letters ◽

10.1016/j.tetlet.2020.152724 ◽

2020 ◽

pp. 152724

Author(s):

Feihua Luo ◽

Shuhua He ◽

Quan Gou ◽

Jinyang Chen ◽

mingzhong Zhang

Keyword(s):

Oxidative Coupling ◽

Benzoic Acids ◽

Efficient Access ◽

Propargyl Alcohols

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Ru(II)-catalyzed Allenylation and Sequential Annulation of N-Tosylbenzamides with Propargyl Alcohols

Chemical Communications ◽

10.1039/d1cc01768c ◽

2021 ◽

Author(s):

Chandra MR Volla ◽

Shreemoyee Kumar ◽

Akshay Murali Nair

Keyword(s):

Propargyl Alcohols

We hereby report a Ru(II)-catalyzed C(sp2)-H allenylation of N-tosylbenzamides to access multi-substituted allenylamides. Furthermore, the allenylamides were converted to the corresponding isoquinolone derivatives via base mediated annulation. The current protocol...

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Direct acylamination of quinoline, isoquinoline, benzimidazole, pyridazine, and pyrimidine 1-oxides. Novel 1,5-sigmatropic shift

The Journal of Organic Chemistry ◽

10.1021/jo00889a009 ◽

1975 ◽

Vol 40 (1) ◽

pp. 41-47 ◽

Cited By ~ 29

Author(s):

R. A. Abramovitch ◽

R. B. Rogers ◽

G. M. Singer

Keyword(s):

Sigmatropic Shift

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ChemInform Abstract: Enantioselective Synthesis of Propargyl Alcohols as Multifunctional Synthons

ChemInform ◽

10.1002/chin.200848265 ◽

2008 ◽

Vol 39 (48) ◽

Author(s):

J. S. Yadav ◽

S. Chandrasekhar

Keyword(s):

Enantioselective Synthesis ◽

Propargyl Alcohols

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Central–axial–central chirality transfer: asymmetric synthesis of highly substituted indenes bearing a stereogenic quaternary carbon center from optically active propargyl alcohols

Chemical Communications ◽

10.1039/c4cc08034c ◽

2015 ◽

Vol 51 (2) ◽

pp. 380-383 ◽

Cited By ~ 27

Author(s):

Masahiro Egi ◽

Kaori Shimizu ◽

Marin Kamiya ◽

Yuya Ota ◽

Shuji Akai

Keyword(s):

Asymmetric Synthesis ◽

Optically Active ◽

Quaternary Carbon ◽

Chirality Transfer ◽

Propargyl Alcohols

An asymmetric synthesis of highly substituted indenes has been developed via the central–axial–central chirality transfer from optically active propargyl alcohols.

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