ChemInform Abstract: THE STEREOSPECIFIC SYNTHESIS OF NEUTRAL AND CATIONIC TERTIARY PHOSPHINE COMPLEXES OF PLATINUM(II)

1974 ◽  
Vol 5 (18) ◽  
pp. no-no
Author(s):  
KEITH R. DIXON ◽  
KENNETH C. MOSS ◽  
MARTIN A. R. SMITH
Keyword(s):  
Stereospecific Synthesis ◽  
Tertiary Phosphine ◽  
Phosphine Complexes

The Stereospecific Synthesis of Neutral and Cationic Tertiary Phosphine Complexes of Platinum(II)

1974 ◽  
Vol 52 (4) ◽  
pp. 692-695 ◽  
Author(s):  
Keith R. Dixon ◽  
Kenneth C. Moss ◽  
Martin A. R. Smith
Keyword(s):  
Synthetic Methods ◽  
Stereospecific Synthesis ◽  
Tertiary Phosphine ◽  
Phosphine Complexes ◽  
Square Planar ◽  
Cleavage Reactions ◽  
Cis And Trans

Stereospecific synthetic methods for the preparation of complexes of the type cis- and trans[PtClL(PEt3)2]+ and cis-[PtClX(PEt3)2] have been developed. Preparations of complexes where L = py, PPh3, PClPh2, or P(OPh)3 and X = SCN, NO2, NO3, N3, NCO, or Br are described and it is shown that bridge cleavage reactions in square planar platinum(II) complexes occur with retention of stereo chemistry.

The synthesis and characterisation of some divinyldisiloxane—(tertiary phosphine) complexes of platinum(0) and nickel(0)

1997 ◽  
Vol 528 (1-2) ◽  
pp. 185-190 ◽  
Author(s):  
Peter B. Hitchcock ◽  
Michael F. Lappert ◽  
Calum MacBeath ◽  
Fiona P.E. Scott ◽  
Nicholas J.W. Warhurst
Keyword(s):  
Tertiary Phosphine ◽  
Phosphine Complexes
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