The Stereospecific Synthesis of Neutral and Cationic Tertiary Phosphine Complexes of Platinum(II)
Keyword(s):
Stereospecific synthetic methods for the preparation of complexes of the type cis- and trans[PtClL(PEt3)2]+ and cis-[PtClX(PEt3)2] have been developed. Preparations of complexes where L = py, PPh3, PClPh2, or P(OPh)3 and X = SCN, NO2, NO3, N3, NCO, or Br are described and it is shown that bridge cleavage reactions in square planar platinum(II) complexes occur with retention of stereo chemistry.
1973 ◽
Vol 51
(10)
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pp. 1634-1644
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Keyword(s):
1966 ◽
Vol 88
(4)
◽
pp. 752-761
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The Carboxylation of cis- and trans-2-Butenyl-2-lithium. A Stereospecific Synthesis of Angelic Acid1
1954 ◽
Vol 76
(7)
◽
pp. 1902-1906
◽
1992 ◽
pp. 1407-1410
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