ChemInform Abstract: A NOVEL METHOD FOR THE OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS TO CARBONYL COMPOUNDS

1975 ◽  
Vol 6 (6) ◽  
pp. no-no
Author(s):  
Y. S. RAO ◽  
R. FILLER
Keyword(s):  
Carbonyl Compounds ◽  
Secondary Alcohols ◽  
Novel Method

scholarly journals Hydrogen Borrowing Catalysis with Secondary Alcohols: A New Route for the Generation of β-Branched Carbonyl Compounds

2017 ◽  
Vol 139 (7) ◽  
pp. 2577-2580 ◽  
Author(s):  
Wasim M. Akhtar ◽  
Choon Boon Cheong ◽  
James R. Frost ◽  
Kirsten E. Christensen ◽  
Neil G. Stevenson ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Secondary Alcohols

Manganese complex-catalysed α-alkylation of ketones with secondary alcohols enables the synthesis of β-branched carbonyl compounds

2020 ◽  
Vol 56 (60) ◽  
pp. 8376-8379 ◽  
Author(s):  
Satyadeep Waiba ◽  
Sayan K. Jana ◽  
Ayan Jati ◽  
Akash Jana ◽  
Biplab Maji
Keyword(s):  
Carbonyl Compounds ◽  
Manganese Complex ◽  
Secondary Alcohols

Diverse β-functionalised carbonyl compounds were synthesized via a manganese(i) complex-catalysed α-alkylation of ketones with secondary alcohols.

1-ChIoromethyl-3,5-dimethylpyrazole hydrochloride. A useful synthetic intermediate

1989 ◽  
Vol 67 (7) ◽  
pp. 1144-1147 ◽  
Author(s):  
Alan R. Katritzky ◽  
Jamshed N. Lam
Keyword(s):  
Carbonyl Compounds ◽  
Alkyl Halides ◽  
Nucleophilic Displacement ◽  
Novel Method ◽  
Synthetic Intermediate ◽  
Substituted Pyrazoles

1-Chloromethyl-3,5-dimethylpyrazole hydrochloride readily undergoes nucleophilic displacement with O-, N-, or S-nu-cleophiles. 1-Phenylthiomethyl-3,5-dimethylpyrazole can be lithiated at the CH2 group and reacted with alkyl halides and carbonyl compounds. Desulfurization of the products affords a novel method of preparing N-substituted pyrazoles. Keywords: pyrazole, lithiation, chloromethylazoles, desulfurization.

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