ChemInform Abstract: HYDROGENOLYSIS OF HYDROCARBONS OVER SUPPORTED CATALYSTS DERIVED FROM METAL CARBONYL CLUSTERS

1981 ◽  
Vol 12 (43) ◽  
Author(s):  
A. F. SIMPSON ◽  
R. WHYMAN
Keyword(s):  
Supported Catalysts ◽  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters

Platinum Supported Catalysts Prepared from Metal Carbonyl Clusters for Hydrocarbons Conversion

1998 ◽  
Vol 549 ◽  
Author(s):  
P.E. Kolosov ◽  
N.B. Shitova ◽  
M.D. Smolikov ◽  
V.A. Drozdov ◽  
E.M. Moroz
Keyword(s):  
Supported Catalysts ◽  
Metal Carbonyl ◽  
Distribution Functions ◽  
Carbonyl Clusters ◽  
Metal Support Interaction ◽  
Cyclohexane Dehydrogenation ◽  
Metal Carbonyl Clusters ◽  
Metal Support ◽  
Dehydrogenation Reactions ◽  
Pt Carbonyl Clusters

AbstractThe investigation of surface Pt/alumina, Pt/ carbon (Sibunit) and Pt/SiO2 species prepared by anchoring of Pt carbonyl clusters of various nuclearity as precursors for high dispersive and thermostable platinum supported catalysts for hydrocarbons conversion, using RDF (radial distribution functions) and chemisorption methods, has shown strong metal-support interaction with formation of Pt/alumina phase with highly dispersed (practically monoatomic) and homogeneously distributed Pt atoms onto alumina surface. The catalytic properties were studied in methane oxidation and cyclohexane dehydrogenation reactions.

Salts of Anionic Metal Carbonyl Clusters with Cryptand[2.2.2](Na+ ), DB-18-crown-6(Na+ ), and Paramagnetic Cp*2 Cr+ Cations Obtained by Reduction

2019 ◽  
Vol 645 (4) ◽  
pp. 472-483 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Alexey V. Kuzmin ◽  
Roman S. Galkin ◽  
Salavat S. Khasanov ◽  
Rinat F. Kurbanov ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters

scholarly journals The Categorization and Structural Prediction of Transition Metal Carbonyl Clusters Using 14n Series Numerical Matrix

2016 ◽  
Vol 8 (1) ◽  
pp. 109
Author(s):  
Enos Masheija Rwantale Kiremire
Keyword(s):  
Transition Metal ◽  
Valence Electron ◽  
Metal Carbonyl ◽  
Electron Content ◽  
Constant Number ◽  
Carbonyl Clusters ◽  
Structural Prediction ◽  
Metal Carbonyl Clusters ◽  
The Matrix ◽  
Special Case

<p>A matrix table of valence electron content of carbonyl clusters has been created using the 14n-based series. The numbers so generated form an array of series which conform precisely with valence electron contents of carbonyl clusters. The renowned 18 electron rule is a special case of 14n+4 series. Similarly, the 16 electron rule is another special case of the 14n+2 series. Categorization of the carbonyl clusters using the matrix table of series has been demonstrated. The table is so organized that clusters numerically represented can easily be compared and analyzed. The numbers that are diagonally arranged from right to left represent capping series. The row from right to left represents a decrease in valence electron content with increase in cluster linkages. The variation of cluster shapes of constant number of skeletal elements especially four or more may be monitored or compared with the variation with the valence electron content.</p>

Synthesis, Characterization and Electrochemistry of Some Metal Carbonyl Clusters Derived from Ferrocenylethynylpyridine

2015 ◽  
Vol 26 (2) ◽  
pp. 461-471 ◽  
Author(s):  
Wai-Yeung Wong ◽  
Qingchen Dong ◽  
Suk-Ha Cheung ◽  
Pui-Ling Lau ◽  
Nian-Yong Zhu ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters

Supported Metal Carbonyl Clusters: Decomposition to Metals and Reactivity

1979 ◽  
pp. 579-601 ◽  
Author(s):  
R. Ugo ◽  
R. Psaro ◽  
G. M. Zanderighi ◽  
J. M. Basset ◽  
A. Theolier ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters ◽  
Supported Metal

Effect of Hydrogen Atoms on the Structures of Trinuclear Metal Carbonyl Clusters: Trinuclear Manganese Carbonyl Hydrides

2009 ◽  
Vol 48 (10) ◽  
pp. 4580-4591 ◽  
Author(s):  
Xian-mei Liu ◽  
Chao-yang Wang ◽  
Qian-shu Li ◽  
Yaoming Xie ◽  
R. Bruce King ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Hydrogen Atoms ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters ◽  
Manganese Carbonyl
Sign in / Sign up

Export Citation Format

Share Document