ChemInform Abstract: METAL CARBONYL CLUSTERS IN THE CATALYTIC HYDROGENATION OF CARBON MONOXIDE

1985 ◽  
Vol 16 (45) ◽  
Author(s):  
J. ZWART ◽  
R. SNEL
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Hydrogenation ◽  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters ◽  
Hydrogenation Of Carbon Monoxide

Methanation of carbon monoxide and dioxide by supported metal carbonyl clusters

1983 ◽  
Vol 61 (6) ◽  
pp. 1306-1308 ◽  
Author(s):  
H. E. Ferkul ◽  
J. M. Berlie ◽  
D. J. Stanton ◽  
J. D. McCowan ◽  
M. C. Baird
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Metal Carbonyl ◽  
Carbon Monoxide Hydrogenation ◽  
Carbonyl Clusters ◽  
Ruthenium Carbonyl ◽  
Ruthenium Carbonyl Clusters ◽  
Metal Carbonyl Clusters ◽  
Carbon Dioxide Methanation ◽  
Methanation Catalyst

The catalysis of carbon monoxide hydrogenation by supported cobalt and ruthenium clusters is studied, and an unusually specific cobalt methanation catalyst is described. A variety of ruthenium carbonyl clusters catalyzes carbon monoxide methanation, irrespective of support, and Ru3(CO)12 on γ-alumina is found to be a potentially useful carbon dioxide methanation catalyst.

Salts of Anionic Metal Carbonyl Clusters with Cryptand[2.2.2](Na+ ), DB-18-crown-6(Na+ ), and Paramagnetic Cp*2 Cr+ Cations Obtained by Reduction

2019 ◽  
Vol 645 (4) ◽  
pp. 472-483 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Alexey V. Kuzmin ◽  
Roman S. Galkin ◽  
Salavat S. Khasanov ◽  
Rinat F. Kurbanov ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters

scholarly journals The Categorization and Structural Prediction of Transition Metal Carbonyl Clusters Using 14n Series Numerical Matrix

2016 ◽  
Vol 8 (1) ◽  
pp. 109
Author(s):  
Enos Masheija Rwantale Kiremire
Keyword(s):  
Transition Metal ◽  
Valence Electron ◽  
Metal Carbonyl ◽  
Electron Content ◽  
Constant Number ◽  
Carbonyl Clusters ◽  
Structural Prediction ◽  
Metal Carbonyl Clusters ◽  
The Matrix ◽  
Special Case

<p>A matrix table of valence electron content of carbonyl clusters has been created using the 14n-based series. The numbers so generated form an array of series which conform precisely with valence electron contents of carbonyl clusters. The renowned 18 electron rule is a special case of 14n+4 series. Similarly, the 16 electron rule is another special case of the 14n+2 series. Categorization of the carbonyl clusters using the matrix table of series has been demonstrated. The table is so organized that clusters numerically represented can easily be compared and analyzed. The numbers that are diagonally arranged from right to left represent capping series. The row from right to left represents a decrease in valence electron content with increase in cluster linkages. The variation of cluster shapes of constant number of skeletal elements especially four or more may be monitored or compared with the variation with the valence electron content.</p>

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